A highly active and durable electrocatalyst for large current density hydrogen evolution reaction

doi:10.1016/j.scib.2019.10.024

IMR OpenIR

	A highly active and durable electrocatalyst for large current density hydrogen evolution reaction
	Xue, Sen 1,2; Liu, Zhibo 2; Ma, Chaoqun 2; Cheng, Hui-Ming 2,3,4; Ren, Wencai 2,3
通讯作者	Cheng, Hui-Ming(cheng@imr.ac.cn) ; Ren, Wencai(wcren@imr.ac.cn)
	2020-01-30
发表期刊	SCIENCE BULLETIN
ISSN	2095-9273
卷号	65 期号:2 页码:123-130
摘要	Splitting water under large current density is essential for efficient large-scale production and commercial utilization of hydrogen. However, the performance of the available electrocatalysts for hydrogen evolution reaction (HER) is far from satisfactory under large current density in alkaline electrolyte. Here we report a remarkably active and durable electrocatalyst, long and dense MoS2/Ni3S2 co-axial heterostructure nanowires on nickel foam (NF). Notably, it requires only 182 and 200 mV overpotential to achieve large current density of 500 and 1000 mA cm(-2), respectively, in alkaline solution, which are far superior to those of Pt/C-NF (281 and 444 mV) and the reported best non-noble metal catalysts (191 and 220 mV). The physical origin for this extraordinary HER performance is analyzed, which provides a useful guide for structure design of electrocatalysts to further improve their performance. (C) 2019 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.
关键词	MoS2/Ni3S2 nanowire Co-axial heterostructure Large current density HER Alkaline electrolyte
资助者	National Natural Science Foundation of China ; Chinese Academy of Sciences ; Liaoning Revitalization Talents Program ; Program for Guangdong Introducing Innovative and Enterpreneurial Teams ; Development and Reform Commission of Shenzhen Municipality for the development of the Low-Dimensional Materials and Devicesdiscipline, and the Economic, Trade and Information Commission of Shenzhen Municipality for the 2017 Graphene Manufacturing Innova
DOI	10.1016/j.scib.2019.10.024
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51325205] ; National Natural Science Foundation of China[51290273] ; National Natural Science Foundation of China[51521091] ; National Natural Science Foundation of China[51861135201] ; Chinese Academy of Sciences[XDB30000000] ; Chinese Academy of Sciences[ZDBS-LY-JSC027] ; Liaoning Revitalization Talents Program[XLYC1808013] ; Program for Guangdong Introducing Innovative and Enterpreneurial Teams[2017ZT07C341] ; Development and Reform Commission of Shenzhen Municipality for the development of the Low-Dimensional Materials and Devicesdiscipline, and the Economic, Trade and Information Commission of Shenzhen Municipality for the 2017 Graphene Manufacturing Innova[201901171523]
WOS研究方向	Science & Technology - Other Topics
WOS类目	Multidisciplinary Sciences
WOS记录号	WOS:000508009300007
出版者	ELSEVIER
引用统计	被引频次：76[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/136596
专题	中国科学院金属研究所
通讯作者	Cheng, Hui-Ming; Ren, Wencai
作者单位	1.Northeastern Univ, Sch Mat Sci & Engn, Shenyang 110819, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 4.Tsinghua Univ, Tsinghua Berkeley Shenzhen Inst TBSI, Shenzhen 518055, Peoples R China
推荐引用方式 GB/T 7714	Xue, Sen,Liu, Zhibo,Ma, Chaoqun,et al. A highly active and durable electrocatalyst for large current density hydrogen evolution reaction[J]. SCIENCE BULLETIN,2020,65(2):123-130.
APA	Xue, Sen,Liu, Zhibo,Ma, Chaoqun,Cheng, Hui-Ming,&Ren, Wencai.(2020).A highly active and durable electrocatalyst for large current density hydrogen evolution reaction.SCIENCE BULLETIN,65(2),123-130.
MLA	Xue, Sen,et al."A highly active and durable electrocatalyst for large current density hydrogen evolution reaction".SCIENCE BULLETIN 65.2(2020):123-130.