| Suppressing lithium dendrite formation by slowing its desolvation kinetics | |
| Yang, Huicong1,2; Yin, Lichang1,2; Shi, Huifa3,4; He, Kuang1,2; Cheng, Hui-Ming1,2,5; Li, Feng1,2 | |
| Corresponding Author | Li, Feng(fli@imr.ac.cn) |
| 2019-11-14 | |
| Source Publication | CHEMICAL COMMUNICATIONS
 |
| ISSN | 1359-7345 |
| Volume | 55Issue:88Pages:13211-13214 |
| Abstract | Slowing the dendrite formation process is one way to alleviate the fast capacity fade and safety issues in lithium metal battery systems. We used tetraethylene glycol dimethyl ether (TEGDME) as a complementary solvent to increase the desolvation activation energy of Li+, reduce the speed of lithium electrodeposition kinetics, and suppress dendrite formation. Density functional theory calculations combined with Raman spectroscopy indicate that a stronger coordination interaction is obtained between Li+ and TEGDME than between Li+ and 1,2-dimethoxyethane (DME) or 1,3-dioxolane (DOL). Such a strong coordination leads to a slower electrochemical reaction rate. As a result, uniform lithium electrodeposition morphology and good cycling stability of a Li vertical bar Li symmetric cell for more than 500 hours were achieved. Our approach suggests a way in which dendrite formation can be controlled by the electrochemical reaction itself. |
| Funding Organization | National Key R&D Program of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Science ; Bureau of Industry and Information Technology of Shenzhen |
| DOI | 10.1039/c9cc07092c |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Key R&D Program of China[2016YFB0100100] ; National Natural Science Foundation of China[51525206] ; National Natural Science Foundation of China[51521091] ; Strategic Priority Research Program of Chinese Academy of Science[XDA22010602] ; Bureau of Industry and Information Technology of Shenzhen[201901171523] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000517258000001 |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/137480 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Li, Feng |
| Affiliation | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Tsinghua Univ, Grad Sch Shenzhen, Shenzhen Key Lab Graphene Based Mat, Engn Lab Functionalized Carbon Mat, Shenzhen 518055, Peoples R China 4.Tsinghua Univ, Sch Mat Sci & Engn, Lab Adv Mat, Beijing 100084, Peoples R China 5.Tsinghua Univ, Tsinghua Berkeley Shenzhen Inst, Shenzhen Geim Graphene Ctr, Shenzhen 518055, Peoples R China |
| Recommended Citation GB/T 7714 | Yang, Huicong,Yin, Lichang,Shi, Huifa,et al. Suppressing lithium dendrite formation by slowing its desolvation kinetics[J]. CHEMICAL COMMUNICATIONS,2019,55(88):13211-13214. |
| APA | Yang, Huicong,Yin, Lichang,Shi, Huifa,He, Kuang,Cheng, Hui-Ming,&Li, Feng.(2019).Suppressing lithium dendrite formation by slowing its desolvation kinetics.CHEMICAL COMMUNICATIONS,55(88),13211-13214. |
| MLA | Yang, Huicong,et al."Suppressing lithium dendrite formation by slowing its desolvation kinetics".CHEMICAL COMMUNICATIONS 55.88(2019):13211-13214. |
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