Nanostructured boron-doped diamond electrode for seawater salinity detection

doi:10.1016/j.apsusc.2020.145652

IMR OpenIR

	Nanostructured boron-doped diamond electrode for seawater salinity detection
	Shi, Dan 1,2; Huang, Nan 1; Liu, Lusheng 1; Yang, Bing 1; Zhai, Zhaofeng 1,2; Wang, Yibao 3; Yuan, Ziyao 1,2; Li, Hong 4; Gai, Zhigang 3; Jiang, Xin 1
通讯作者	Huang, Nan(nhuang@imr.ac.cn) ; Gai, Zhigang(zhiganggai@126.com) ; Jiang, Xin(xjiang@imr.ac.cn)
	2020-05-15
发表期刊	APPLIED SURFACE SCIENCE
ISSN	0169-4332
卷号	512 页码:8
摘要	Electrodes with high response and stability are urgently required to reach a steady and accurate measurement of seawater salinity. Herein, boron-doped diamond (BDD) is for the first time considered as a promising alternative to commercial platinum black in seawater salinity detection due to their considerable conductivity and outstanding stability. However, the intrinsical low double layer capacitance (DLC) of planar BDD film (BDDF) electrodes affect their response in the detection. To solve these problems, boron-doped diamond nanorod forest (BDDNF) electrodes are fabricated via hot filament chemical vapor deposition. Noted, four orders of magnitude larger of DLC (2820 mu F/cm(2)) than BDDF (0.35 mu F/cm(2)) is achieved on BDDNF due to a much enhanced electroactive surface area which is calculated to be 1.47 times larger than BDDF. Benefited from the enhanced DLC and accelerating diffusion resulted by the nanostructure, the response of BDDNF exhibits an enhancement by a factor of 1.5 compared to BDDF at the salinity of 40 %o. Moreover, in striking contrast to commercial platinum black electrode, the obtained BDDNF electrodes exhibit outstanding stability thanks to the increased amount of carbon oxygen functional groups on BDDNF surface. This work greatly promises the potential applications of BDDNF electrodes in seawater salinity detection.
关键词	Boron-doped diamond Double-layer capacitor Nanorod forest Salinity Seawater Conductivity electrode
资助者	Joint Research Fund Liaoning-Shenyang National Laboratory for Materials Science ; GDAS' Special Project of Science and Technology Development
DOI	10.1016/j.apsusc.2020.145652
收录类别	SCI
语种	英语
资助项目	Joint Research Fund Liaoning-Shenyang National Laboratory for Materials Science[2018510009] ; GDAS' Special Project of Science and Technology Development[2018GDASCX-0402]
WOS研究方向	Chemistry ; Materials Science ; Physics
WOS类目	Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:000522731700053
出版者	ELSEVIER
引用统计	被引频次：9[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/137870
专题	中国科学院金属研究所
通讯作者	Huang, Nan; Gai, Zhigang; Jiang, Xin
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, 72 Wenhua Rd, Shenyang 110016, Peoples R China 3.Qilu Univ Technol, Shandong Acad Sci, Inst Oceanog Instrumentat, 37 Miaoling Rd, Qingdao 266001, Peoples R China 4.Guangdong Inst New Mat, Changxing Rd 363, Guangzhou 510650, Peoples R China
推荐引用方式 GB/T 7714	Shi, Dan,Huang, Nan,Liu, Lusheng,et al. Nanostructured boron-doped diamond electrode for seawater salinity detection[J]. APPLIED SURFACE SCIENCE,2020,512:8.
APA	Shi, Dan.,Huang, Nan.,Liu, Lusheng.,Yang, Bing.,Zhai, Zhaofeng.,...&Jiang, Xin.(2020).Nanostructured boron-doped diamond electrode for seawater salinity detection.APPLIED SURFACE SCIENCE,512,8.
MLA	Shi, Dan,et al."Nanostructured boron-doped diamond electrode for seawater salinity detection".APPLIED SURFACE SCIENCE 512(2020):8.