New insight into the negative difference effect in aluminium corrosion using in-situ electrochemical ICP-OES

doi:10.1016/j.corsci.2020.108568

IMR OpenIR

	New insight into the negative difference effect in aluminium corrosion using in-situ electrochemical ICP-OES
	Yu, Yingjie 1,3; Li, Ying 1,2
通讯作者	Li, Ying(liying@imr.ac.cn)
	2020-05-15
发表期刊	CORROSION SCIENCE
ISSN	0010-938X
卷号	168 页码:9
摘要	Hydrogen evolution and dissolution of Aluminium (Al) have been investigated at different anodic potentials in de-oxygenated 3.5 % NaCl electrolyte to afford new insights into its negative difference effect (NDE). Innovatory to previous reports, the instantaneous concentration of dissolved Al3+ ions was detected using a novel in-situ electrochemical ICP-OES technique and a dissolution stoichiometry of n = 3 was observed, thereby precluding the Al intermediate ion mechanism. The effects of the local pH and the surface film's breakdown area on the hydrogen evolution rate were investigated quantitatively, which suggests that the NDE of Al results from the combined effects of these two factors.
关键词	Aluminium ICP-OES Anodic dissolution Hydrogen evolution Negative difference effect
资助者	National Natural Science Fund of China
DOI	10.1016/j.corsci.2020.108568
收录类别	SCI
语种	英语
资助项目	National Natural Science Fund of China[51671198]
WOS研究方向	Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目	Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号	WOS:000525871400019
出版者	PERGAMON-ELSEVIER SCIENCE LTD
引用统计	被引频次：18[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/138209
专题	中国科学院金属研究所
通讯作者	Li, Ying
作者单位	1.Chinese Acad Sci, Inst Met Res, Corros & Protect Div, Wencui Rd 62, Shenyang 110016, Peoples R China 2.Northeastern Univ, Shenyang Natl Lab Mat Sci, 3-11 Wenhua Rd, Shenyang 110819, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Technol, Wenhua Rd 72, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Yu, Yingjie,Li, Ying. New insight into the negative difference effect in aluminium corrosion using in-situ electrochemical ICP-OES[J]. CORROSION SCIENCE,2020,168:9.
APA	Yu, Yingjie,&Li, Ying.(2020).New insight into the negative difference effect in aluminium corrosion using in-situ electrochemical ICP-OES.CORROSION SCIENCE,168,9.
MLA	Yu, Yingjie,et al."New insight into the negative difference effect in aluminium corrosion using in-situ electrochemical ICP-OES".CORROSION SCIENCE 168(2020):9.