All-Solid-State Planar Sodium-Ion Microcapacitors with Multidirectional Fast Ion Diffusion Pathways

doi:10.1002/advs.201902147

IMR OpenIR

	All-Solid-State Planar Sodium-Ion Microcapacitors with Multidirectional Fast Ion Diffusion Pathways
	Zheng, Shuanghao 1,2,3; Wang, Sen 1,3; Dong, Yanfeng 1; Zhou, Feng 1; Qin, Jieqiong 1,3; Wang, Xiao 1; Su, Feng 1,3; Sun, Chenglin 1; Wu, Zhong-Shuai 1; Cheng, Hui-Ming 4,5; Bao, Xinhe 1,2
通讯作者	Wu, Zhong-Shuai(wuzs@dicp.ac.cn)
	2019-12-04
发表期刊	ADVANCED SCIENCE
卷号	6 期号:23 页码:9
摘要	With the relentless development of smart and miniaturized electronics, the worldwide thirst for microscale electrochemical energy storage devices with form factors is launching a new era of competition. Herein, the first prototype planar sodium-ion microcapacitors (NIMCs) are constructed based on the interdigital microelectrodes of urchin-like sodium titanate as faradaic anode and nanoporous activated graphene as non-faradaic cathode along with high-voltage ionogel electrolyte on a single flexible substrate. By effectively coupling with battery-type anode and capacitor-type cathode, the resultant all-solid-state NIMCs working at 3.5 V exhibit a high volumetric energy density of 37.1 mWh cm(-3) and an ultralow self- discharge rate of 44 h from V-max to 0.6 V-max, both of which surpass most reported hybrid micro-supercapacitors. Through tuning graphene layer covered on the top surface of interdigital microelectrodes, the NIMCs unveil remarkably enhanced power density, owing to the establishment of favorable multidirectional fast ion diffusion pathways that significantly reduce the charge transfer resistance. Meanwhile, the as-fabricated NIMCs present excellent mechanical flexibility without capacitance fade under repeated deformation, and electrochemical stability at a high temperature of 80 degrees C because of using nonflammable ionogel electrolyte and in-plane geometry. Therefore, these flexible planar NIMCs with multidirectional ion diffusion pathways hold tremendous potential for microelectronics.
关键词	energy storage flexible in-plane geometry ionogel electrolytes sodium-ion microcapacitors
资助者	National Natural Science Foundation of China ; National Key R@D Program of China ; LiaoNing Revitalization Talents Program ; Natural Science Foundation of Liaoning Province ; DICP ; Dalian National Laboratory For Clean Energy (DNL), CAS, DICPQIBEBT ; DNL Cooperation Fund, CAS ; Exploratory Research Program of Shaanxi Yanchang Petroleum (Group) CO., LTD ; DICP, China Postdoctoral Science Foundation
DOI	10.1002/advs.201902147
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51572259] ; National Natural Science Foundation of China[51872283] ; National Natural Science Foundation of China[21805273] ; National Key R@D Program of China[2016YBF0100100] ; LiaoNing Revitalization Talents Program[XLYC1807153] ; Natural Science Foundation of Liaoning Province[20180510038] ; DICP[DICP ZZBS201708] ; DICP[DICP ZZBS201802] ; Dalian National Laboratory For Clean Energy (DNL), CAS, DICPQIBEBT[DICPQIBEBT UN201702] ; DNL Cooperation Fund, CAS[DNL180310] ; DNL Cooperation Fund, CAS[DNL180308] ; Exploratory Research Program of Shaanxi Yanchang Petroleum (Group) CO., LTD ; DICP, China Postdoctoral Science Foundation[2018M631831] ; DICP, China Postdoctoral Science Foundation[2018M633497]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目	Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000528033800007
出版者	WILEY
引用统计	被引频次：41[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/138420
专题	中国科学院金属研究所
通讯作者	Wu, Zhong-Shuai
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China 4.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China 5.Tsinghua Berkeley Shenzhen Inst, Shenzhen Geim Graphene Ctr, 1001 Xueyuan Rd, Shenzhen 518055, Peoples R China
推荐引用方式 GB/T 7714	Zheng, Shuanghao,Wang, Sen,Dong, Yanfeng,et al. All-Solid-State Planar Sodium-Ion Microcapacitors with Multidirectional Fast Ion Diffusion Pathways[J]. ADVANCED SCIENCE,2019,6(23):9.
APA	Zheng, Shuanghao.,Wang, Sen.,Dong, Yanfeng.,Zhou, Feng.,Qin, Jieqiong.,...&Bao, Xinhe.(2019).All-Solid-State Planar Sodium-Ion Microcapacitors with Multidirectional Fast Ion Diffusion Pathways.ADVANCED SCIENCE,6(23),9.
MLA	Zheng, Shuanghao,et al."All-Solid-State Planar Sodium-Ion Microcapacitors with Multidirectional Fast Ion Diffusion Pathways".ADVANCED SCIENCE 6.23(2019):9.