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Photoelectrochemical Glucose Biosensor Based on the Heterogeneous Facets of Nanocrystalline TiO2/Au/Glucose Oxidase Films
Yang, Wenke1; Xu, Wei1,2; Wang, Yadong1; Chen, Delun1; Wang, Xiaohong1; Cao, Yang1; Wu, Qiang3,4; Tu, Jinchun1; Zhen, Chao2
Corresponding AuthorTu, Jinchun(tujinchun@hainu.edu.cn) ; Zhen, Chao(czhen@imr.ac.cn)
2020-03-01
Source PublicationACS APPLIED NANO MATERIALS
ISSN2574-0970
Volume3Issue:3Pages:2723-2732
AbstractTiO2 single-crystal nanomaterials with highly reactive surfaces have attracted widespread attention due to their fundamental aspects and industrial applications. However, many previous studies have ignored the poor photoelectric efficiency of TiO2 nanomaterials originating from a mismatch in the diffusion distance of electrons and holes as well as migration rates of holes and electrons. Therefore, suppression of hole migration could enhance the photoelectrochemical performance of TiO2. In this work, single-crystal anatase TiO2 nanomaterials with (001) facets were successfully prepared. The results suggested that some (101) facets were retained by the modified fluoride ion crystal facet control process. Subsequently, fluorine-free and Au-containing crystal facets were obtained by annealing and electrochemical deposition. In addition, the propensity for adsorption of Au on a TiO2 (101) surface was verified by first-principles quantum chemical calculations. Electrochemical impedance spectroscopy and UV-visible spectrophotometry showed the presence of a large area (001), conducive to better enzyme affinity. Biosensors prepared by carrier self-separation derived from natural different facets and Au nanoparticles (TiO2 (001)/Au/GOx) achieved high sensitivities reaching 16.86 mu A mM(-1) cm(-2), an extended linear range (0.01-3 mM), and a low detection limit (0.83 mu M). In summary, the proposed route allowed for the first time the use of nanocrystal engineering in the construction of glucose biosensors with satisfactory performances, which is promising for the future fabrication of high-performance biosensors.
KeywordTiO2 (001) facets Au glucose oxidase PEC biosensor nanocrystal engineering
Funding OrganizationKey Research and Development Project of Hainan Province ; National Natural Science Foundation of China
DOI10.1021/acsanm.0c00086
Indexed BySCI
Language英语
Funding ProjectKey Research and Development Project of Hainan Province[ZDYF2018106] ; National Natural Science Foundation of China[51762012] ; National Natural Science Foundation of China[81860373]
WOS Research AreaScience & Technology - Other Topics ; Materials Science
WOS SubjectNanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS IDWOS:000526396200064
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/138531
Collection中国科学院金属研究所
Corresponding AuthorTu, Jinchun; Zhen, Chao
Affiliation1.Haitian Univ, State Key Lab Marine Resource Utilizat South Chin, Coll Mat Sci & Engn, Haikou 570228, Hainan, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
3.Hainan Med Univ, Chinese Acad Med Sci, Key Lab Emergency & Trauma, Minist Educ, Haikou 571199, Hainan, Peoples R China
4.Hainan Med Univ, Res Unit Isl Emergency Med, Chinese Acad Med Sci, Haikou 571199, Hainan, Peoples R China
Recommended Citation
GB/T 7714
Yang, Wenke,Xu, Wei,Wang, Yadong,et al. Photoelectrochemical Glucose Biosensor Based on the Heterogeneous Facets of Nanocrystalline TiO2/Au/Glucose Oxidase Films[J]. ACS APPLIED NANO MATERIALS,2020,3(3):2723-2732.
APA Yang, Wenke.,Xu, Wei.,Wang, Yadong.,Chen, Delun.,Wang, Xiaohong.,...&Zhen, Chao.(2020).Photoelectrochemical Glucose Biosensor Based on the Heterogeneous Facets of Nanocrystalline TiO2/Au/Glucose Oxidase Films.ACS APPLIED NANO MATERIALS,3(3),2723-2732.
MLA Yang, Wenke,et al."Photoelectrochemical Glucose Biosensor Based on the Heterogeneous Facets of Nanocrystalline TiO2/Au/Glucose Oxidase Films".ACS APPLIED NANO MATERIALS 3.3(2020):2723-2732.
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