Preliminary study of microstructure, mechanical properties and corrosion resistance of antibacterial Ti-15Zr-xCu alloy for dental C application

doi:10.1016/j.jmst.2020.03.003

IMR OpenIR

	Preliminary study of microstructure, mechanical properties and corrosion resistance of antibacterial Ti-15Zr-xCu alloy for dental C application
	Kolawole, Sharafadeen Kunle 1,2,4; Hai, Wang 2; Zhang, Shuyuan 2; Sun, Ziqing 2; Siddiqui, Muhammad Ali 1,2; Ullah, Ihsan 1,2; Song, Wei 2; Witte, Frank 3; Yang, Ke 2
通讯作者	Yang, Ke(kyang@imr.ac.cn)
	2020-08-01
发表期刊	JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
ISSN	1005-0302
卷号	50 页码:31-43
摘要	Ti-15Zr-xCu (3 <= x <= 7, wt.%) novel antibacterial and antibiofilm alloys with competitive mechanical properties, biological responses and corrosion resistance were designed and fabricated. Annealing heat treatment on Ti-15Zr-7Cu (TZC-7A), after holding for 2 hat slightly above their beta transus temperature (BTT) ensured their tensile strength (UTS), yield strength (YS) and hardness (HRV) were improved by 31.2%, 20% and 12.3% respectively compared to the control without Cu, Ti-15Zr (T-15ZA). Although the 3 wt.% Cu alloy displayed the highest elongation (26%), the TZC-7A alloy also possessed a good ductility. Presence of evenly dispersed Ti2Cu and Zr2Cu Cu-rich intermetallic phases formed as interwoven and alternating lamellae within the alpha + beta matrix as a result of Cu addition, as revealed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). These greatly contributed to their strengthening and bactericidal properties. Over 98% antibacterial effect against E. coli and S. aureus have been imparted, coupled with excellent biofilm inhibition. Potentiodynamic polarization curves showed that the TZC-7A alloy possessed higher corrosion resistance than commercially pure titanium, cp-Ti; contact angle test revealed enhanced hydrophilicity; while confocal laser scanning microscopy (CLSM) and cell counting kit (CCK-8) assays also displayed drastically lowered bacterial adhesion rate with comparatively no cytotoxicity. Cell attachment on all alloys was similar but the best spread was obtained on TZC-7A after 24 h. The developed alloy has good potential as an antibacterial implant material with combination of optimized properties. (C) 2020 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
关键词	Ti-Zr alloy Cu addition Antibacterial Mechanical properties Intermetallic phases
资助者	National Key Research and Development Program of China ; National NaturalScience Foundation ; Youth Innovation Promotion Association, CAS ; Promoting Liaoning Province Talents Program-Top Young Talents ; CAS-TWAS President Fellowship
DOI	10.1016/j.jmst.2020.03.003
收录类别	SCI
语种	英语
资助项目	National Key Research and Development Program of China[2018YFC1106601] ; National Key Research and Development Program of China[2016YFC1100600] ; National NaturalScience Foundation[51631009] ; Youth Innovation Promotion Association, CAS[2014168] ; Promoting Liaoning Province Talents Program-Top Young Talents[XLYC1807069] ; CAS-TWAS President Fellowship
WOS研究方向	Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目	Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号	WOS:000537588800004
出版者	JOURNAL MATER SCI TECHNOL
引用统计	被引频次：34[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/139052
专题	中国科学院金属研究所
通讯作者	Yang, Ke
作者单位	1.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China 3.Dept Prosthodont Geriatr Dent & Craniomandibular, Assmannshauser Str 4-6, D-14197 Berlin, Germany 4.Fed Polytech, PMB 420, Offa, Kwara State, Nigeria
推荐引用方式 GB/T 7714	Kolawole, Sharafadeen Kunle,Hai, Wang,Zhang, Shuyuan,et al. Preliminary study of microstructure, mechanical properties and corrosion resistance of antibacterial Ti-15Zr-xCu alloy for dental C application[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2020,50:31-43.
APA	Kolawole, Sharafadeen Kunle.,Hai, Wang.,Zhang, Shuyuan.,Sun, Ziqing.,Siddiqui, Muhammad Ali.,...&Yang, Ke.(2020).Preliminary study of microstructure, mechanical properties and corrosion resistance of antibacterial Ti-15Zr-xCu alloy for dental C application.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,50,31-43.
MLA	Kolawole, Sharafadeen Kunle,et al."Preliminary study of microstructure, mechanical properties and corrosion resistance of antibacterial Ti-15Zr-xCu alloy for dental C application".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 50(2020):31-43.