Corrosion Behavior of Damaged Epoxy Coated Steel Bars Under the Coupling Effect of Chloride Ion and Carbonization

doi:10.11900/0412.1961.2019.00302

IMR OpenIR

	Corrosion Behavior of Damaged Epoxy Coated Steel Bars Under the Coupling Effect of Chloride Ion and Carbonization
	Wei Jie 1; Wei Yinghua 2; Li Jing 2; Zhao Hongtao 2; Lv Chenxi 2; Dong Junhua 1; Ke Wei 3; He Xiaoyan 3
通讯作者	Dong Junhua(jhdong@imr.ac.cn)
	2020-06-01
发表期刊	ACTA METALLURGICA SINICA
ISSN	0412-1961
卷号	56 期号:6 页码:885-897
摘要	It is unavoidable for coated steel bars to be scratched during transportation and construction, which will lead to the damage of coating and exposure of steel matrix. Consequently, the corrosion resistance of coated steel bars after damage will directly affect the durability of structures. The corrosion evolution behavior of damaged epoxy coated steel bars under the coupling action of chloride ion and carbonization was studied by comparing with bare steel bars and perfectly coated steel bars. On the basis of characterizing the composition and structural characteristics of epoxy coating, the corrosion morphology and product composition at the damage site of the coating were analyzed by CLSM and Raman spectroscopy, and the corrosion process was monitored by corrosion potential and electrochemical impedance spectroscopy to reveal the dynamic of corrosion evolution. The results show that the epoxy coating without damage has a good protective effect on steel matrix, and no corrosion occurs during long-term immersion in all six solutions including the chloride ions and carbonization corrosive environments. The corrosion activation or passivation behavior of damaged coated steel bars is consistent with that of uncoated bare bars, which is obviously affected by chloride ion and carbonization. Passivation occurs in the system without Cl- and with pH of 12.6 or 9.8. Activation dissolution occurs in the chloride-free system with pH of 9.2, and in the system of different pH values with 0.6 mol/L NaCl. In the active systems, the corrosion rate increases with time. In the chloride-free system, the corrosion products after long-term corrosion are mainly alpha-FeOOH, while in the chloride-containing system with different pH, the corrosion products contain not only alpha-FeOOH, but also beta-FeOOH and a small amount of Fe3O4. Under the coupling action of chloride ion and carbonization, the corrosion of damaged coated steel bars occurs only in the damaged site, and the corrosion extends towards to the depth of the matrix, which will not cause the peeling of coatings in other sites.
关键词	epoxy coated steel bar corrosion evolution chloride ion carbonization
资助者	National Natural Science Foundation of China ; Strategic Priority Research Program of Chinese Academy of Sciences ; Shenyang Key Research and Development and Technology Transfer Program
DOI	10.11900/0412.1961.2019.00302
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51501201] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDA13040501] ; Shenyang Key Research and Development and Technology Transfer Program
WOS研究方向	Metallurgy & Metallurgical Engineering
WOS类目	Metallurgy & Metallurgical Engineering
WOS记录号	WOS:000546975500009
出版者	SCIENCE PRESS
引用统计	被引频次：6[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/139668
专题	中国科学院金属研究所
通讯作者	Dong Junhua
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Res & Dev Ctr Adv Mat, Shenyang 110016, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Environm Corros Ctr, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Wei Jie,Wei Yinghua,Li Jing,et al. Corrosion Behavior of Damaged Epoxy Coated Steel Bars Under the Coupling Effect of Chloride Ion and Carbonization[J]. ACTA METALLURGICA SINICA,2020,56(6):885-897.
APA	Wei Jie.,Wei Yinghua.,Li Jing.,Zhao Hongtao.,Lv Chenxi.,...&He Xiaoyan.(2020).Corrosion Behavior of Damaged Epoxy Coated Steel Bars Under the Coupling Effect of Chloride Ion and Carbonization.ACTA METALLURGICA SINICA,56(6),885-897.
MLA	Wei Jie,et al."Corrosion Behavior of Damaged Epoxy Coated Steel Bars Under the Coupling Effect of Chloride Ion and Carbonization".ACTA METALLURGICA SINICA 56.6(2020):885-897.