| Toward Understanding the Enhanced Pseudocapacitive Storage in 3D SnS/MXene Architectures Enabled by Engineered Surface Reactions | |
| Qin, Jinwen1; Hao, Linlin1; Wang, Xin1; Jiang, Yan1; Xie, Xi2; Yang, Rui2; Cao, Minhua1 | |
| Corresponding Author | Cao, Minhua(caomh@bit.edu.cn) |
| 2020-07-28 | |
| Source Publication | CHEMISTRY-A EUROPEAN JOURNAL
 |
| ISSN | 0947-6539 |
| Pages | 11 |
| Abstract | The optimization of three-dimensional (3D) MXene-based electrodes with desired electrochemical performances is highly demanded. Here, a precursor-guided strategy is reported for fabricating the 3D SnS/MXene architecture with tiny SnS nanocrystals (approximate to 5 nm in size) covalently decorated on the wrinkled Ti(3)C(2)T(x)nanosheets through Ti-S bonds (denoted as SnS/Ti3C2Tx-O). The formation of Ti-S bonds between SnS and Ti(3)C(2)T(x)was confirmed by extended X-ray absorption fine structure (EXAFS). Rather than bulky SnS plates decorated on Ti3C2Tx(SnS/Ti3C2Tx-H) by one-step hydrothermal sulfidation followed by post annealing, this SnS/Ti3C2Tx-O presents size-dependent structural and dynamic properties. The as-formed 3D hierarchical structure can provide short ion-diffusion pathways and electron transport distances because of the more accessible surface sites. In addition, benefiting from the tiny SnS nanocrystals that can effectively improve Na(+)diffusion and suppress structural variation upon charge/discharge processes, the as-obtained SnS/Ti3C2Tx-O can generate pseudocapacitance-dominated storage behavior enabled by engineered surface reactions. As predicted, this electrode exhibits an enhanced Na storage capacity of 565 mAh g(-1)at 0.1 A g(-1)after 75 cycles, outperforming SnS/Ti3C2Tx-H (336 mAh g(-1)), SnS (212 mAh g(-1)), and Ti3C2Tx(104 mAh g(-1)) electrodes. |
| Keyword | MXenes nanoparticles precursor-guided synthesis SnS sodium-ion batteries |
| Funding Organization | National Natural Science Foundation of China |
| DOI | 10.1002/chem.202000795 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[21872008] ; National Natural Science Foundation of China[21601014] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000552752400001 |
| Publisher | WILEY-V C H VERLAG GMBH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/139992 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Cao, Minhua |
| Affiliation | 1.Beijing Inst Technol, Sch Chem & Chem Engn, Minist Educ China, Key Lab Cluster Sci, Beijing 100081, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China |
| Recommended Citation GB/T 7714 | Qin, Jinwen,Hao, Linlin,Wang, Xin,et al. Toward Understanding the Enhanced Pseudocapacitive Storage in 3D SnS/MXene Architectures Enabled by Engineered Surface Reactions[J]. CHEMISTRY-A EUROPEAN JOURNAL,2020:11. |
| APA | Qin, Jinwen.,Hao, Linlin.,Wang, Xin.,Jiang, Yan.,Xie, Xi.,...&Cao, Minhua.(2020).Toward Understanding the Enhanced Pseudocapacitive Storage in 3D SnS/MXene Architectures Enabled by Engineered Surface Reactions.CHEMISTRY-A EUROPEAN JOURNAL,11. |
| MLA | Qin, Jinwen,et al."Toward Understanding the Enhanced Pseudocapacitive Storage in 3D SnS/MXene Architectures Enabled by Engineered Surface Reactions".CHEMISTRY-A EUROPEAN JOURNAL (2020):11. |
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