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Oxygen octahedral coupling mediated ferroelectric-antiferroelectric phase transition based on domain wall engineering
Geng, W. R.1,2; Guo, X. W.1,2; Zhu, Y. L.1; Wang, Y. J.1; Tang, Y. L.1; Han, M. J.1,5; Feng, Y. P.1,3; Zou, M. J.1,2; Wu, B.1,2; Ma, J. Y.1,2,4; Hu, W. T.1,2; Ma, X. L.1,4
Corresponding AuthorZhu, Y. L.(ylzhu@imr.ac.cn) ; Tang, Y. L.(yltang@imr.ac.cn) ; Ma, X. L.(xlma@imr.ac.cn)
2020-10-01
Source PublicationACTA MATERIALIA
ISSN1359-6454
Volume198Pages:145-152
AbstractExotic domain-wall phenomena make ferroelectrics the candidates for nanoelectronics. The local symmetry and structure anomalies at domain walls have raised interest in the unusual functionalities, such as domain wall chirality and conductivity. Especially, the spontaneous lattice distortion and symmetry breaking at domain walls activate them as the location of structural transformation. However, the routes to achieve ferroelectric-antiferroelectric phase transition via ferroelectric domain walls remain challenging, which are important to develop materials for energy storage and conversion. Here, we have observed stepwise antiferroelectric phase transition in strained pure BiFeO3 ultrathin films derived from ferroelectric domain walls. Aberration-corrected transmission electron microscopy observation reveals that the resultant phase transition is mediated by dense 180 degrees domain walls via providing the antiparallel cation displacement, cooperating with the enhanced interfacial oxygen octahedral clamping. First-principles calculations further confirm the critical role of interfacial oxygen octahedral coupling during this transition. These findings report an alternative route for antiferroelectric phase transition. Besides, our results provide fresh insights into functionalities of ferroelectric domain walls and open a venue for developing energy-storage materials based on domain engineering. (c) 2020 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
KeywordFerroelectric films Ferroelectric domain walls Antiferroelectric phase transition Oxygen octahedral coupling Scanning transmission electron microscopy
Funding OrganizationKey Research Program of Frontier Sciences CAS ; National Natural Science Foundation of China ; Shenyang National Laboratory for Materials Science ; Youth Innovation Promotion Association CAS
DOI10.1016/j.actamat.2020.08.007
Indexed BySCI
Language英语
Funding ProjectKey Research Program of Frontier Sciences CAS[QYZDJ-SSW-JSC010] ; National Natural Science Foundation of China[51971223] ; National Natural Science Foundation of China[51671194] ; National Natural Science Foundation of China[51922100] ; Shenyang National Laboratory for Materials Science[L2019R06] ; Shenyang National Laboratory for Materials Science[L2019R08] ; Shenyang National Laboratory for Materials Science[L2019F01] ; Shenyang National Laboratory for Materials Science[L2019F13] ; Youth Innovation Promotion Association CAS[2016177]
WOS Research AreaMaterials Science ; Metallurgy & Metallurgical Engineering
WOS SubjectMaterials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS IDWOS:000567798300002
PublisherPERGAMON-ELSEVIER SCIENCE LTD
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/140446
Collection中国科学院金属研究所
Corresponding AuthorZhu, Y. L.; Tang, Y. L.; Ma, X. L.
Affiliation1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Wenhua Rd 72, Shenyang 110016, Peoples R China
2.Univ Sci & Technol China, Jinzhai Rd 96, Hefei 230026, Peoples R China
3.Univ Chinese Acad Sci, Yuquan Rd 19, Beijing 100049, Peoples R China
4.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Langongping Rd 287, Lanzhou 730050, Peoples R China
5.Southern Univ Sci & Technol, Dept Phys, Shenzhen 518055, Peoples R China
Recommended Citation
GB/T 7714
Geng, W. R.,Guo, X. W.,Zhu, Y. L.,et al. Oxygen octahedral coupling mediated ferroelectric-antiferroelectric phase transition based on domain wall engineering[J]. ACTA MATERIALIA,2020,198:145-152.
APA Geng, W. R..,Guo, X. W..,Zhu, Y. L..,Wang, Y. J..,Tang, Y. L..,...&Ma, X. L..(2020).Oxygen octahedral coupling mediated ferroelectric-antiferroelectric phase transition based on domain wall engineering.ACTA MATERIALIA,198,145-152.
MLA Geng, W. R.,et al."Oxygen octahedral coupling mediated ferroelectric-antiferroelectric phase transition based on domain wall engineering".ACTA MATERIALIA 198(2020):145-152.
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