Fabrication of N, S co-doped graphene aerogel for high-performance supercapacitors: pi-conjugated planar molecules as efficient dopants and pillared agents

doi:10.1016/j.apsusc.2020.147022

IMR OpenIR

	Fabrication of N, S co-doped graphene aerogel for high-performance supercapacitors: pi-conjugated planar molecules as efficient dopants and pillared agents
	Zhang, Lili 1; Chen, Huaxia 1; Lu, Xingyu 2; Wang, Yun 1; Tan, Lili 3; Sui, Dianpeng 1; Qi, Wei 2
通讯作者	Sui, Dianpeng(sdp2596@sina.com) ; Qi, Wei(wqi@imr.ac.cn)
	2020-11-01
发表期刊	APPLIED SURFACE SCIENCE
ISSN	0169-4332
卷号	529 页码:9
摘要	Rational constructing carbon electrode materials with heteroatoms (eg. N, S, B, F) and high surface area is essencial to the appealing performance of supercapacitor (SC). Here we present a novel fabrication strategy for sandwich-like N, S co-doped three-dimensional (3D) porous graphene aerogels (NSGAs) via one-pot hydro thermal method for high performance SCs materials. The unique advantage of the proposed synthesis strategy is the applications of 2, 5-Dimercapto-1, 3, 4-thiadiazole (DMTD) as bifunctional pillared agents and efficient dopant precursors. The planar DMTD molecules have shown strong supramolecular pi-pi and H-bonding interactions with graphene oxide (GO), thus avoiding the restacking of graphene sheets and enhancing the doping efficiency and amount of S atoms, which are beneficial to the SC performance of NSGA. The synthesized NSGA samples exhibit the atomic content of S up to 2.39 at.% with surface area at 366.0 m(2) g(-1), and display a maximum energy density of 10.52 W h kg(-1) for assembled symmetric supercapacitor. The relatively high tandem device performance with a remarkable current response, even at 2000 mV s(-1), reaches the top level for graphene-based SC system. The proposed simple fabrication strategy and attracting performance of NSGA material shed light on the potential practical applications of graphene-based material as SCs, and the observed structure-function relations also provides physical-chemical insight into the function principle of heteroatom doped graphene in SCs.
关键词	Supercapacitors Graphene aerogel Heteroatom N S co-doping Supramolecular interactions Hydrothermal method 2,5-Dimercapto-1, 3, 4-thiadiazole
资助者	NSFC of China ; Youth Innovation Promotion Association, CAS, China ; Shaanxi Joint Laboratory of Graphene (Northwestern Polytechnical University), China
DOI	10.1016/j.apsusc.2020.147022
收录类别	SCI
语种	英语
资助项目	NSFC of China[21761132010] ; NSFC of China[91645114] ; NSFC of China[21573256] ; NSFC of China[41303086] ; Youth Innovation Promotion Association, CAS, China ; Shaanxi Joint Laboratory of Graphene (Northwestern Polytechnical University), China[2018002]
WOS研究方向	Chemistry ; Materials Science ; Physics
WOS类目	Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:000568723800009
出版者	ELSEVIER
引用统计	被引频次：44[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/140534
专题	中国科学院金属研究所
通讯作者	Sui, Dianpeng; Qi, Wei
作者单位	1.Northeastern Univ, Dept Chem, Coll Sci, Shenyang 110819, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Northwestern Polytech Univ, Shaanxi Joint Lab Graphene, Xian 710072, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Lili,Chen, Huaxia,Lu, Xingyu,et al. Fabrication of N, S co-doped graphene aerogel for high-performance supercapacitors: pi-conjugated planar molecules as efficient dopants and pillared agents[J]. APPLIED SURFACE SCIENCE,2020,529:9.
APA	Zhang, Lili.,Chen, Huaxia.,Lu, Xingyu.,Wang, Yun.,Tan, Lili.,...&Qi, Wei.(2020).Fabrication of N, S co-doped graphene aerogel for high-performance supercapacitors: pi-conjugated planar molecules as efficient dopants and pillared agents.APPLIED SURFACE SCIENCE,529,9.
MLA	Zhang, Lili,et al."Fabrication of N, S co-doped graphene aerogel for high-performance supercapacitors: pi-conjugated planar molecules as efficient dopants and pillared agents".APPLIED SURFACE SCIENCE 529(2020):9.