Giant room-temperature barocaloric effect at the electronic phase transition in Ni1-xFexS

doi:10.1039/c9mh01976f

IMR OpenIR

	Giant room-temperature barocaloric effect at the electronic phase transition in Ni1-xFexS
	Lin, Jianchao 1; Tong, Peng 1; Zhang, Xuekai 1; Wang, Zichen 1; Zhang, Zhao 2,3; Li, Bing 2,3; Zhong, Guohua 4; Chen, Jie 5; Wu, Yaoda 5; Lu, Huaile 5; He, Lunhua 5; Bai, Bo 5; Ling, Langsheng 6; Song, Wenhai 1; Zhang, Zhidong 2,3; Sun, Yuping 1,6
通讯作者	Tong, Peng(tongpeng@issp.ac.cn) ; Li, Bing(bingli@imr.ac.cn) ; Zhong, Guohua(gh.zhong@siat.ac.cn)
	2020-10-01
发表期刊	MATERIALS HORIZONS
ISSN	2051-6347
卷号	7 期号:10 页码:2690-2695
摘要	Barocaloric (BC) materials are a type of promising solid-state refrigerant that can be used in future refrigerators. Besides the routine pressure-driven lattice entropy change, spin or polar degrees of freedom often make considerable contributions. Relatively, little attention has been paid to the electronic contribution. Here we demonstrate a sizable electronic entropy change under pressure in hexagonal Ni1-xFexS due to the remarkable modification of its electronic structure. Accordingly, the total entropy change reaches 52.8 J kg(-1)K(-1)under only 100 MPa, which places Ni1-xFexS among the giant BC materials. Again, because of the electronic contribution, the thermal conductivity of Ni1-xFexS is higher than the reported values of other giant BC materials, which can boost the cooling efficiency. Our work would inspire the study of the giant BC effect with good thermal conductance in a wide range of electronic phase transition materials.
资助者	Chinese Academy of Sciences (CAS) ; National Natural Science Foundation of China ; Users with Excellence Program of Hefei Science Center CAS ; CAS ; Basic Research Program of Shenzhen
DOI	10.1039/c9mh01976f
收录类别	SCI
语种	英语
资助项目	Chinese Academy of Sciences (CAS)[QYZDB-SSW-SLH015] ; National Natural Science Foundation of China[U1932127] ; Users with Excellence Program of Hefei Science Center CAS[2019HSC-UE008] ; CAS ; Basic Research Program of Shenzhen[JCYJ20170818153404696]
WOS研究方向	Chemistry ; Materials Science
WOS类目	Chemistry, Multidisciplinary ; Materials Science, Multidisciplinary
WOS记录号	WOS:000575959700011
出版者	ROYAL SOC CHEMISTRY
引用统计	被引频次：37[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/140807
专题	中国科学院金属研究所
通讯作者	Tong, Peng; Li, Bing; Zhong, Guohua
作者单位	1.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China 4.Chinese Acad Sci, Shenzhen Inst Adv Technol, Shenzhen 518055, Peoples R China 5.Spallat Neutron Source Sci Ctr, Dongguan 523803, Peoples R China 6.Chinese Acad Sci, Anhui Prov Key Lab Condensed Matter Phys Extreme, High Magnet Field Lab, Hefei 230031, Peoples R China
推荐引用方式 GB/T 7714	Lin, Jianchao,Tong, Peng,Zhang, Xuekai,et al. Giant room-temperature barocaloric effect at the electronic phase transition in Ni1-xFexS[J]. MATERIALS HORIZONS,2020,7(10):2690-2695.
APA	Lin, Jianchao.,Tong, Peng.,Zhang, Xuekai.,Wang, Zichen.,Zhang, Zhao.,...&Sun, Yuping.(2020).Giant room-temperature barocaloric effect at the electronic phase transition in Ni1-xFexS.MATERIALS HORIZONS,7(10),2690-2695.
MLA	Lin, Jianchao,et al."Giant room-temperature barocaloric effect at the electronic phase transition in Ni1-xFexS".MATERIALS HORIZONS 7.10(2020):2690-2695.