Oxygen assisted butanol conversion on bifunctional carbon nanotube catalysts: Activity of oxygen functionalities

doi:10.1016/j.carbon.2020.08.053

IMR OpenIR

	Oxygen assisted butanol conversion on bifunctional carbon nanotube catalysts: Activity of oxygen functionalities
	Li, Fan 1,2; Yan, Pengqiang 1; Herold, Felix 3; Drochner, Alfons 3; Wang, Haihua 1; Cao, Tianlong 1; Liu, Weijie 1,2; Dai, Xueya 1,2; Zhang, Bingsen 1,2; Etzold, Bastian J. M.3; Qi, Wei 1,2
通讯作者	Etzold, Bastian J. M.(etzold@tcl.tu-darmstadt.de) ; Qi, Wei(wqi@imr.ac.cn)
	2020-12-01
发表期刊	CARBON
ISSN	0008-6223
卷号	170 页码:580-588
摘要	Catalytic conversion of n-butanol to high-value-added product is considered as a highly important route towards biomass derived fine chemicals. The present work reports the applications of non-metallic multi-walled carbon nanotube (CNT) as bifunctional catalysts for oxygen assisted n-butanol conversion reactions. Oxidative dehydrogenation (ODH) and dehydration of n-butanol on CNT yielded aldehyde and alkene compounds via redox and acid catalytic routes, respectively. CNT exhibited high activity (over 50% n-butanol conversion) and stability (over 120 h) under gentle reaction conditions (<330 degrees C), which are competitive to conventional metal-based catalysts. Carboxylic acid groups were identified as catalytic active sites for dehydration reactions via linking the reactivity (kinetic parameters) with the surface composition and structural information of CNT catalysts. The redox activity could be related to ketonic carbonyl groups, and interestingly the intrinsic ODH catalytic activity is also influenced by degree of graphitization for CNT materials. (C) 2020 Elsevier Ltd. All rights reserved.
关键词	n-Butanol conversion Oxidative dehydrogenation Carbon catalysis Oxygen functionalities Reaction mechanism and kinetics
资助者	NSFC of China ; Youth Innovation Promotion Association, CAS, China ; Natural Science Foundation of Liaoning Province of China ; Deutsche Bundesstiftung Umwelt (DBU) ; Deutsche Forschungsgemeinschaft (DFG, German Research Foundation)
DOI	10.1016/j.carbon.2020.08.053
收录类别	SCI
语种	英语
资助项目	NSFC of China[21761132010] ; NSFC of China[91645114] ; NSFC of China[21573256] ; Youth Innovation Promotion Association, CAS, China ; Natural Science Foundation of Liaoning Province of China[2020-YQ-02] ; Deutsche Bundesstiftung Umwelt (DBU) ; Deutsche Forschungsgemeinschaft (DFG, German Research Foundation)[ET-101/13-1]
WOS研究方向	Chemistry ; Materials Science
WOS类目	Chemistry, Physical ; Materials Science, Multidisciplinary
WOS记录号	WOS:000579779800057
出版者	PERGAMON-ELSEVIER SCIENCE LTD
引用统计	被引频次：20[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/140953
专题	中国科学院金属研究所
通讯作者	Etzold, Bastian J. M.; Qi, Wei
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Tech Univ Darmstadt, Ernst Berl Inst Tech & Makromol Chem, D-64287 Darmstadt, Germany
推荐引用方式 GB/T 7714	Li, Fan,Yan, Pengqiang,Herold, Felix,et al. Oxygen assisted butanol conversion on bifunctional carbon nanotube catalysts: Activity of oxygen functionalities[J]. CARBON,2020,170:580-588.
APA	Li, Fan.,Yan, Pengqiang.,Herold, Felix.,Drochner, Alfons.,Wang, Haihua.,...&Qi, Wei.(2020).Oxygen assisted butanol conversion on bifunctional carbon nanotube catalysts: Activity of oxygen functionalities.CARBON,170,580-588.
MLA	Li, Fan,et al."Oxygen assisted butanol conversion on bifunctional carbon nanotube catalysts: Activity of oxygen functionalities".CARBON 170(2020):580-588.