Hydrogenolysis of Aryl Ether Bond over Heterogeneous Cobalt-Based Catalyst

doi:10.1021/acs.iecr.0c01374

IMR OpenIR

	Hydrogenolysis of Aryl Ether Bond over Heterogeneous Cobalt-Based Catalyst
	Zhang, Lijie 1; Wang, Yongzhao 2; Zhang, Li 1; Chi, Zixin 1; Yang, Yanling 1; Zhang, Zhaoxia 1; Zhang, Bingsen 2; Lin, Jingdong 1; Wan, Shaolong 1
通讯作者	Wan, Shaolong(swan@xmu.edu.cn)
	2020-09-30
发表期刊	INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN	0888-5885
卷号	59 期号:39 页码:17357-17364
摘要	The development of efficient non-noble metal catalysts is of critical importance for conversion of lignin toward value-added chemicals. The trans-metal Co catalysts and the counterparts promoted with a small amount of Ru were found highly selective for hydrogenolysis of lignin-derived aromatic ethers in decalin at relatively mild conditions. The physical and chemical properties of the as-prepared catalysts were fully investigated by various characterization methods, and Co species was found well dispersed in the reduced catalysts. The experimental results showed that Co/CeO2 could selectively cleave the C-O bonds of diphenyl ether (DPE) to produce benzene and phenol, which can be further converted to cyclohexane and cyclohexanol. Upon 5Co/CeO2, 97% selectivity to those C-O bond ruptured products was achieved, while the direct hydrogenation products including dicyclohexyl ether and cyclohexyl account for only 3%. Moreover, benzene, featured as a typical intermediate product, could reach a maximum yield of 27.4% at around 80% conversion. The addition of a small amount of Ru (0.1 wt % and below) could significantly accelerate the hydrogenolysis reactivity but also result in the declined selectivity of benzene during the reaction due to the stronger hydrogenation ability.
资助者	Major Research Plan of National Natural Science Foundation of China ; National Natural Science Foundations of China ; 985 Program of the Chemistry and Chemical Engineering disciplines of Xiamen University
DOI	10.1021/acs.iecr.0c01374
收录类别	SCI
语种	英语
资助项目	Major Research Plan of National Natural Science Foundation of China[91545114] ; Major Research Plan of National Natural Science Foundation of China[91545203] ; National Natural Science Foundations of China[21576227] ; 985 Program of the Chemistry and Chemical Engineering disciplines of Xiamen University
WOS研究方向	Engineering
WOS类目	Engineering, Chemical
WOS记录号	WOS:000577113500044
出版者	AMER CHEMICAL SOC
引用统计	被引频次：23[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/141060
专题	中国科学院金属研究所
通讯作者	Wan, Shaolong
作者单位	1.Xiamen Univ, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Lijie,Wang, Yongzhao,Zhang, Li,et al. Hydrogenolysis of Aryl Ether Bond over Heterogeneous Cobalt-Based Catalyst[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2020,59(39):17357-17364.
APA	Zhang, Lijie.,Wang, Yongzhao.,Zhang, Li.,Chi, Zixin.,Yang, Yanling.,...&Wan, Shaolong.(2020).Hydrogenolysis of Aryl Ether Bond over Heterogeneous Cobalt-Based Catalyst.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,59(39),17357-17364.
MLA	Zhang, Lijie,et al."Hydrogenolysis of Aryl Ether Bond over Heterogeneous Cobalt-Based Catalyst".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 59.39(2020):17357-17364.