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Titanium-Modified MIL-101(Cr) Derived Titanium-Chromium-Oxide as Highly Efficient Oxidative Desulfurization Catalyst
Li, Xiaolin1,2; Zhang, Liang1; Sun, Yinyong3
Corresponding AuthorZhang, Liang(zhangliang@szpt.edu.cn) ; Sun, Yinyong(yysun@hit.edu.cn)
2020-09-01
Source PublicationCATALYSTS
Volume10Issue:9Pages:10
AbstractA titanium-chromium-oxide catalyst was prepared by a facile calcination of titanium-modified MIL-101(Cr). The resulting material, possessing a surface area of 60 m(2)g(-1)and a titania content of 50.0 wt%, can be directly used as the catalyst for oxidative desulfurization (ODS) reaction of dibenzothiophene (DBT). This novel ODS catalyst can remove 900 ppm sulfur-containing compounds in a reaction time of 30 min at 60 degrees C. The experimental results showed that the specific activity increased with the titanium content. The specific activity of the catalyst with 50%Ti reached 129 mu mol/m(2), which was much higher than that of reported Ti-based catalysts.
KeywordMIL-101(Cr) anatase titania DBT oxidative desulfurization
Funding OrganizationPost-Doctoral Foundation Project of Shenzhen Polytechnic ; Guangdong Basic and Applied Basic Research Foundation ; Post-doctoral Later-stage Foundation Project of Shenzhen Polytechnic
DOI10.3390/catal10091091
Indexed BySCI
Language英语
Funding ProjectPost-Doctoral Foundation Project of Shenzhen Polytechnic[6019330009K0] ; Guangdong Basic and Applied Basic Research Foundation[2019A1515110532] ; Post-doctoral Later-stage Foundation Project of Shenzhen Polytechnic[6019271003K]
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
WOS IDWOS:000580563000001
PublisherMDPI
Citation statistics
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/141080
Collection中国科学院金属研究所
Corresponding AuthorZhang, Liang; Sun, Yinyong
Affiliation1.Shenzhen Polytech, Postdoctoral Innovat Pract Base, Inst Intelligent Mfg Technol, Shenzhen 518055, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
3.Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Peoples R China
Recommended Citation
GB/T 7714
Li, Xiaolin,Zhang, Liang,Sun, Yinyong. Titanium-Modified MIL-101(Cr) Derived Titanium-Chromium-Oxide as Highly Efficient Oxidative Desulfurization Catalyst[J]. CATALYSTS,2020,10(9):10.
APA Li, Xiaolin,Zhang, Liang,&Sun, Yinyong.(2020).Titanium-Modified MIL-101(Cr) Derived Titanium-Chromium-Oxide as Highly Efficient Oxidative Desulfurization Catalyst.CATALYSTS,10(9),10.
MLA Li, Xiaolin,et al."Titanium-Modified MIL-101(Cr) Derived Titanium-Chromium-Oxide as Highly Efficient Oxidative Desulfurization Catalyst".CATALYSTS 10.9(2020):10.
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