Titanium-Modified MIL-101(Cr) Derived Titanium-Chromium-Oxide as Highly Efficient Oxidative Desulfurization Catalyst | |
Li, Xiaolin1,2; Zhang, Liang1; Sun, Yinyong3 | |
Corresponding Author | Zhang, Liang(zhangliang@szpt.edu.cn) ; Sun, Yinyong(yysun@hit.edu.cn) |
2020-09-01 | |
Source Publication | CATALYSTS
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Volume | 10Issue:9Pages:10 |
Abstract | A titanium-chromium-oxide catalyst was prepared by a facile calcination of titanium-modified MIL-101(Cr). The resulting material, possessing a surface area of 60 m(2)g(-1)and a titania content of 50.0 wt%, can be directly used as the catalyst for oxidative desulfurization (ODS) reaction of dibenzothiophene (DBT). This novel ODS catalyst can remove 900 ppm sulfur-containing compounds in a reaction time of 30 min at 60 degrees C. The experimental results showed that the specific activity increased with the titanium content. The specific activity of the catalyst with 50%Ti reached 129 mu mol/m(2), which was much higher than that of reported Ti-based catalysts. |
Keyword | MIL-101(Cr) anatase titania DBT oxidative desulfurization |
Funding Organization | Post-Doctoral Foundation Project of Shenzhen Polytechnic ; Guangdong Basic and Applied Basic Research Foundation ; Post-doctoral Later-stage Foundation Project of Shenzhen Polytechnic |
DOI | 10.3390/catal10091091 |
Indexed By | SCI |
Language | 英语 |
Funding Project | Post-Doctoral Foundation Project of Shenzhen Polytechnic[6019330009K0] ; Guangdong Basic and Applied Basic Research Foundation[2019A1515110532] ; Post-doctoral Later-stage Foundation Project of Shenzhen Polytechnic[6019271003K] |
WOS Research Area | Chemistry |
WOS Subject | Chemistry, Physical |
WOS ID | WOS:000580563000001 |
Publisher | MDPI |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/141080 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Zhang, Liang; Sun, Yinyong |
Affiliation | 1.Shenzhen Polytech, Postdoctoral Innovat Pract Base, Inst Intelligent Mfg Technol, Shenzhen 518055, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Peoples R China |
Recommended Citation GB/T 7714 | Li, Xiaolin,Zhang, Liang,Sun, Yinyong. Titanium-Modified MIL-101(Cr) Derived Titanium-Chromium-Oxide as Highly Efficient Oxidative Desulfurization Catalyst[J]. CATALYSTS,2020,10(9):10. |
APA | Li, Xiaolin,Zhang, Liang,&Sun, Yinyong.(2020).Titanium-Modified MIL-101(Cr) Derived Titanium-Chromium-Oxide as Highly Efficient Oxidative Desulfurization Catalyst.CATALYSTS,10(9),10. |
MLA | Li, Xiaolin,et al."Titanium-Modified MIL-101(Cr) Derived Titanium-Chromium-Oxide as Highly Efficient Oxidative Desulfurization Catalyst".CATALYSTS 10.9(2020):10. |
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