| Designed Iron Single Atom Catalysts for Highly Efficient Oxygen Reduction Reaction in Alkaline and Acid Media | |
| Zhao, Shiyong1; Zhang, Lianji2; Johannessen, Bernt3; Saunders, Martin4,5; Liu, Chang6; Yang, Shi-Ze7; Jiang, San Ping1 | |
| Corresponding Author | Liu, Chang(cliu@imr.ac.cn) ; Jiang, San Ping(s.jiang@curtin.edu.au) |
| 2020-12-03 | |
| Source Publication | ADVANCED MATERIALS INTERFACES
 |
| ISSN | 2196-7350 |
| Pages | 8 |
| Abstract | Single atom catalysts (SACs) have attracted much attentions due to their advantages of high catalysis efficiency and excellent selectivity. However, for industrial applications, synthesis of SACs in large and practical quantities is very important. The challenge is to develop synthesis methods with controllability and scalability. Herein, a well-characterized and scalable method is demonstrated to synthesize atomically dispersed iron atoms coordinated with nitrogen on graphene, SAFe @ NG, with high atomic loading (approximate to 4.6 wt%) through a one-pot pyrolysis process. The method is scalable for the fabrication of Fe SACs with high quantities. The Fe-N-G catalyst exhibits high intrinsic oxygen reduction reaction (ORR) performance, reaching half potential of 0.876 and 0.702 V in alkaline and acidic solutions, respectively, with excellent microstructure stability. Furthermore, the density functional theory (DFT) simulation confirms that the Fe atoms in coordination with four nitrogen atoms, FeN4, in graphene is the active center for the 4-electron ORR process. This work demonstrates an efficient design pathway for single atom catalysts as highly active and stable electrocatalysts for high-performance ORR applications. |
| Keyword | controllable and scalable synthesis Fe single‐ atom catalysts FeN4 active center oxygen reduction reaction |
| Funding Organization | Australian Research Council Discovery Project Funding Scheme ; University of Western Australia - Australian Research Council LIEF grant ; National Natural Science Foundation of China ; U.S. Department of Energy, Office of Science, Basic Energy Sciences, Materials Science and Engineering ; ORNL's Center for Nanophase Materials Sciences ; Scientific User Facilities Division of U.S. Department of Energy |
| DOI | 10.1002/admi.202001788 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Australian Research Council Discovery Project Funding Scheme[DP180100568] ; Australian Research Council Discovery Project Funding Scheme[DP180100731] ; University of Western Australia - Australian Research Council LIEF grant[LE120100026] ; National Natural Science Foundation of China[51521091] ; National Natural Science Foundation of China[51872293] ; U.S. Department of Energy, Office of Science, Basic Energy Sciences, Materials Science and Engineering ; ORNL's Center for Nanophase Materials Sciences ; Scientific User Facilities Division of U.S. Department of Energy |
| WOS Research Area | Chemistry ; Materials Science |
| WOS Subject | Chemistry, Multidisciplinary ; Materials Science, Multidisciplinary |
| WOS ID | WOS:000595209300001 |
| Publisher | WILEY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/141425 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Liu, Chang; Jiang, San Ping |
| Affiliation | 1.Curtin Univ, WA Sch Mines Minerals Energy & Chem Engn, Perth, WA 6102, Australia 2.Zhengzhou Univ, Sch Mat Sci & Engn, Zhengzhou 450001, Peoples R China 3.Australian Synchrotron, Clayton, Vic 3168, Australia 4.Univ Western Australia, Ctr Microscopy Characterizat & Anal CMCA, Perth, WA 6009, Australia 5.Univ Western Australia, Sch Mol Sci, Perth, WA 6009, Australia 6.Chinese Acad Sci, Inst Met Res, Adv Carbon Div, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 7.Arizona State Univ, Eyring Mat Ctr, Tempe, AZ 85287 USA |
| Recommended Citation GB/T 7714 | Zhao, Shiyong,Zhang, Lianji,Johannessen, Bernt,et al. Designed Iron Single Atom Catalysts for Highly Efficient Oxygen Reduction Reaction in Alkaline and Acid Media[J]. ADVANCED MATERIALS INTERFACES,2020:8. |
| APA | Zhao, Shiyong.,Zhang, Lianji.,Johannessen, Bernt.,Saunders, Martin.,Liu, Chang.,...&Jiang, San Ping.(2020).Designed Iron Single Atom Catalysts for Highly Efficient Oxygen Reduction Reaction in Alkaline and Acid Media.ADVANCED MATERIALS INTERFACES,8. |
| MLA | Zhao, Shiyong,et al."Designed Iron Single Atom Catalysts for Highly Efficient Oxygen Reduction Reaction in Alkaline and Acid Media".ADVANCED MATERIALS INTERFACES (2020):8. |
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