Effect of Double Transition Metal Salt Catalyst on Fushun Oil Shale Pyrolysis

doi:10.1155/2020/6685299

IMR OpenIR

	Effect of Double Transition Metal Salt Catalyst on Fushun Oil Shale Pyrolysis
	Liu, Xiaoyang 1; Pan, Haodan 1; Guo, Chuang 2; Di, Xiaojing 1; Hu, Hongxiang 1
通讯作者	Pan, Haodan(panhaodan@126.com) ; Hu, Hongxiang(hxhu@imr.ac.cn)
	2020-11-04
发表期刊	SCANNING
ISSN	0161-0457
卷号	2020 页码:14
摘要	Shale ash (SA) as the carrier, the ratio of Cu to Ni in the Cu-Ni transition metal salt being, respectively, 1 : 0, 2 : 1, 1 : 1, 1 : 2, 0 : 1, the double transition metal salt catalyst (CumNin/SA) was prepared to explore the effect of such catalysts on the pyrolysis behavior and characteristics of Fushun OS. The research results show that the temperature (Tmax) corresponding to the maximum weight loss rate decreased by 12.9 degrees C, 4.0 degrees C, and 3.6 degrees C; and the apparent activation energy decreased by 35.2%, 33.9%, and 29.6%, respectively, after adding catalysts Cu0Ni1/SA in pyrolysis. The addition of Cu0Ni1/SA and Cu2Ni1/SA further improves the shale oil (SO) yield of 3.5% and 3.1%, respectively. Cu0Ni1/SA produces more aromatic hydrocarbons, which, however, weakens the stability of SO and is of toxicity in use. After analyzing the pyrolysis product-semicoke (SC) and SO-with ATR-FTIR and GC-MS methods, CumNin/SA promotes the secondary cracking and aromatization of OS pyrolysis, increasing the content of the compound of olefins and aromatics in SO, and hastening the decomposition of long-chain aliphatic hydrocarbons to short-chain aliphatic hydrocarbons.
DOI	10.1155/2020/6685299
收录类别	SCI
语种	英语
WOS研究方向	Instruments & Instrumentation ; Microscopy
WOS类目	Instruments & Instrumentation ; Microscopy
WOS记录号	WOS:000593579100001
出版者	WILEY-HINDAWI
引用统计	被引频次：5[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/141461
专题	中国科学院金属研究所
通讯作者	Pan, Haodan; Hu, Hongxiang
作者单位	1.Liaoning Shihua Univ, Coll Petr Engn, Fushun 113301, Peoples R China 2.Beijing Gas Energy Dev Co Ltd, Beijing 100000, Peoples R China 3.Chinese Acad Sci, Inst Met Res, CAS Key Lab Nucl Mat & Safety Assessment, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Liu, Xiaoyang,Pan, Haodan,Guo, Chuang,et al. Effect of Double Transition Metal Salt Catalyst on Fushun Oil Shale Pyrolysis[J]. SCANNING,2020,2020:14.
APA	Liu, Xiaoyang,Pan, Haodan,Guo, Chuang,Di, Xiaojing,&Hu, Hongxiang.(2020).Effect of Double Transition Metal Salt Catalyst on Fushun Oil Shale Pyrolysis.SCANNING,2020,14.
MLA	Liu, Xiaoyang,et al."Effect of Double Transition Metal Salt Catalyst on Fushun Oil Shale Pyrolysis".SCANNING 2020(2020):14.