Effect of phthalocyanine coordination compound doping on the luminescent oxygen quenching of pyrene/polysilicone coatings

IMR OpenIR

	Effect of phthalocyanine coordination compound doping on the luminescent oxygen quenching of pyrene/polysilicone coatings
其他题名	Effect of Phthalocyanine Coordination Compound Doping on the Luminescent Oxygen Quenching of Pyrene/polysilicone Coatings
	Jin BiQing 1; Jia DeMin 1; Shi Yi 2; Chen LiuSheng 2; Zhang YongCun 3
	2008
发表期刊	ACTA CHIMICA SINICA
ISSN	0567-7351
卷号	66 期号:10 页码:1168-1172
摘要	Polymer films containing luminescent dyes are widely used in oxygen sensors. In this work, metal-free phthalocyanine (Pc) and several Pc coordination compounds, including Mg-Pc, AlCl-Pc, Si(OH)(2)-Pc and Cu-Pc, were individually doped into pyrene/polysilicone coatings and then their luminescent oxygen quenching behavior was compared to that of dope-free one. It was experimentally observed that the doping of all the Pc coordination compounds into the coatings showed excellent Stern-Volmer plot linearity, the coatings with Cu-Pc and Si(OH)(2)-Pc resulted in the enhancement of pressure sensitivity, and AlCl-Pc doped one presented the lowest temperature dependence for luminescent oxygen quenching. Those correspond to the micro-environmental polarity of pyrene chromophors in the film, which is proved by the variety of their emission intensity ratio values of I-3/I-1. Furthermore, this behavior is associated with the fluorescence quenching due to the increased spin-orbit interaction between the ions and rings, which considerably reduce the fluorescence intensity by converting them to non-radiative intersystem crossing. Also, the electronic transfer of a planar aromatic structure could be attributed to the increased stability between the dye and dope molecules.
关键词	FILMS SENSORS POLYMER MOLECULES MATRIX luminescent oxygen sensor phthalocyanine coordination compound fluorescence emission oxygen quenching
收录类别	CSCD
语种	英语
CSCD记录号	CSCD:3293617
引用统计	被引频次：1[CSCD] [CSCD记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/146062
专题	中国科学院金属研究所
作者单位	1.中国科学院广州地球化学研究所 2.中国科学院 3.中国科学院金属研究所
推荐引用方式 GB/T 7714	Jin BiQing,Jia DeMin,Shi Yi,et al. Effect of phthalocyanine coordination compound doping on the luminescent oxygen quenching of pyrene/polysilicone coatings[J]. ACTA CHIMICA SINICA,2008,66(10):1168-1172.
APA	Jin BiQing,Jia DeMin,Shi Yi,Chen LiuSheng,&Zhang YongCun.(2008).Effect of phthalocyanine coordination compound doping on the luminescent oxygen quenching of pyrene/polysilicone coatings.ACTA CHIMICA SINICA,66(10),1168-1172.
MLA	Jin BiQing,et al."Effect of phthalocyanine coordination compound doping on the luminescent oxygen quenching of pyrene/polysilicone coatings".ACTA CHIMICA SINICA 66.10(2008):1168-1172.