Synthesis and Photocatalytic Property of N-doped BiVO4 via Sol-Gel Method Using Corn Stem as Template | |
其他题名 | Synthesis and Photocatalytic Property of N-doped BiVO_4 via Sol-Gel Method Using Corn Stem as Template |
Wang Min1; Niu Chao1; Dong ZhanJun2; Che YinSheng1; Dong Duo1; Zheng HaoYan1; Yang ChangXiu1 | |
2014 | |
发表期刊 | JOURNAL OF INORGANIC MATERIALS
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ISSN | 1000-324X |
卷号 | 29期号:8页码:807-813 |
摘要 | N-doped BiVO4 photocatalysts (CS-BiVO4-xN) were successfully prepared by Sol-Gel method taking the corn stem as template and C6H12N4 as N source. The samples were characterized with X-ray diffraction (XRD), X-ray photoelectron spectroscope (XPS), scanning electron microscope (SEM), Fourier infrared spectrum (FTIR), and UV-Vis absorption spectroscope (UV-Vis). The photocatalytic activity were investigated by degradation of methyl oran ge (MO) under visible-light irradiation. The results showed that N doping did not change the crystallinity of the BiVO4. The doped N replaced some of O atoms in BiVO4 and formed the -N-V-O band. The synergetic effect of impurity energy levels and oxygen vacancies led to narrower band-gap and red-shift of optical absorption band. Furthermore, the N doped BiVO4 with honeycomb like structure and smaller crystal sizes was prepared by using corn stem as template, which is beneficial to higher initial MO absorption and better photocatalytic activity. The degradation rate of MO under visible light illumination for 50 min is 80.9% in presence of CS-BiVO4-12N, which is much higher than those in presence of CS-BiVO4 (25.56%) and BiVO4-12N (28.34%). |
关键词 | VISIBLE-LIGHT TIO2-XNX PHOTOCATALYST DEGRADATION N-doped corn stem BiVO4 photocatalyst methyl orange solution |
收录类别 | CSCD |
语种 | 英语 |
资助项目 | [National Natural Science Foundation of China for Youth] |
CSCD记录号 | CSCD:5215079 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/146631 |
专题 | 中国科学院金属研究所 |
作者单位 | 1.沈阳理工大学 2.中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | Wang Min,Niu Chao,Dong ZhanJun,et al. Synthesis and Photocatalytic Property of N-doped BiVO4 via Sol-Gel Method Using Corn Stem as Template[J]. JOURNAL OF INORGANIC MATERIALS,2014,29(8):807-813. |
APA | Wang Min.,Niu Chao.,Dong ZhanJun.,Che YinSheng.,Dong Duo.,...&Yang ChangXiu.(2014).Synthesis and Photocatalytic Property of N-doped BiVO4 via Sol-Gel Method Using Corn Stem as Template.JOURNAL OF INORGANIC MATERIALS,29(8),807-813. |
MLA | Wang Min,et al."Synthesis and Photocatalytic Property of N-doped BiVO4 via Sol-Gel Method Using Corn Stem as Template".JOURNAL OF INORGANIC MATERIALS 29.8(2014):807-813. |
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