Synthesis, Structure and Magnetic Analysis of the Cobalt Polymer Based on N-(3-pyridine)-sulfonylaspartate

IMR OpenIR

	Synthesis, Structure and Magnetic Analysis of the Cobalt Polymer Based on N-(3-pyridine)-sulfonylaspartate
其他题名	Synthesis,Structure and Magnetic Analysis of the Cobalt Polymer Based on N-(3-pyridine)-sulfonyl aspartate
	Jia JingJing 1; Zhang LingKai 2; Li ShiXiong 2; Jiang YiMin 2; Luo Pei 2; Yin XiuJu 2; Liao BeiLing 2
	2017
发表期刊	CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN	0254-5861
卷号	36 期号:2 页码:266-272
摘要	One new cobalt polymer Co(L)center dot 3H(2)O(n) (1, H2L = N-(3-pyridine)-sulfonylas-partate) has been synthesized and characterized by single-crystal X-ray diffraction and elemental analysis. Polymer 1 belongs to the monoclinic system, space group P2(1)/n with a = 11.479(2), b = 7.3180(15), c = 16.424(3) angstrom, beta = 109.56(3)degrees, V = 1300.1(5) angstrom(3), M-r = 385.22, Z = 12, F(000) = 790, S = 1.054, R = 0.0670, wR = 0.1147, (Delta rho)(max) = 1.158 and (Delta rho)(min) = -0.754 e/angstrom(3). TGA showed that the polymer first lost one coordinated water molecule and then another two coordinated water molecules. The values of the Curie and Curie-Weiss constants of polymer 1 are C-m = 2.67 cm(3)mol(-1) K and theta = -21.66 K.
其他摘要	One new cobalt polymer Co(L)·3H_2O_n (1,H_2L = N-(3-pyridine)-sulfonylas-partate) has been synthesized and characterized by single-crystal X-ray diffraction and elemental analysis. Polymer 1 belongs to the monoclinic system, space group P2_1/n with a = 11.479(2), b = 7.3180(15), c= 16.424(3) A,β= 109.56(3)°,V= 1300.1(5)A~3, M_r = 385.22, Z= 12,F(000) = 790,S = 1.054,R = 0.0670,wR = 0.1147,(Ap)_(max) = 1.158 and (?p)min= -0.754 e/A~3. TGA showed that the polymer first lost one coordinated water molecule and then another two coordinated water molecules. The values of the Curie and Curie-Weiss constants of polymer 1 are C_m = 2.67 cm~3 mol~(-1) K and θ = -21.66 K.
关键词	SINGLE-MOLECULE MAGNETS COORDINATION POLYMERS CRYSTAL-STRUCTURE FLUORESCENCE FRAMEWORK COMPLEXES CO(II) polymer structure magnetic N-(3-pyridine)-sulfonylaspartate
收录类别	CSCD
语种	英语
资助项目	[Natural Science Foundation of Guangxi Province] ; [Education Department of Guangxi Province]
CSCD记录号	CSCD:5924371
引用统计	被引频次：1[CSCD] [CSCD记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/146759
专题	中国科学院金属研究所
作者单位	1.中国科学院金属研究所 2.广西师范大学 3.河池学院
推荐引用方式 GB/T 7714	Jia JingJing,Zhang LingKai,Li ShiXiong,et al. Synthesis, Structure and Magnetic Analysis of the Cobalt Polymer Based on N-(3-pyridine)-sulfonylaspartate[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2017,36(2):266-272.
APA	Jia JingJing.,Zhang LingKai.,Li ShiXiong.,Jiang YiMin.,Luo Pei.,...&Liao BeiLing.(2017).Synthesis, Structure and Magnetic Analysis of the Cobalt Polymer Based on N-(3-pyridine)-sulfonylaspartate.CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,36(2),266-272.
MLA	Jia JingJing,et al."Synthesis, Structure and Magnetic Analysis of the Cobalt Polymer Based on N-(3-pyridine)-sulfonylaspartate".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 36.2(2017):266-272.