Prediction of the thermodynamic properties of 1-alkyl-3-methylimidazolium lactate ionic liquids C(n)mimLact (n = 2, 3, 4, 5, and 6) by parachor | |
其他题名 | Prediction of the thermodynamic properties of 1-alkyl-3-methylimidazolium lactate ionic liquids CnmimLact(n=2,3,4,5, and 6)by parachor |
Fang DaWei1; Tong Jing2; Guan Wei2; Wang Han2; Yang JiaZhen1 | |
2010 | |
发表期刊 | SCIENCE CHINA-CHEMISTRY
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ISSN | 1674-7291 |
卷号 | 53期号:12页码:2564-2570 |
摘要 | An ionic liquid (IL) based on lactate, 1-butyl-3-methylimidazolium lactate (C(4)mimLact), has been prepared and characterized by H-1 nuclear magnetic resonance (NMR) spectroscopy and differential scanning calorimetry (DSC). Since the IL can form strong hydrogen bonds with water, trace water is a problematic impurity in the IL. Using the standard addition method (SAM), the density, refractive index and surface tension of C(4)mimLact were measured in the temperature range (308.15 to 343.15 +/- 0.05) K. On the basis of the experimental data, the parachor and molar volume for C(4)mimLact |
其他摘要 | An ionic liquid(IL)based on lactate,1-butyl-3-methylimidazolium lactate(C4mimLact), has been prepared and characterized by ~1H nuclear magnetic resonance(NMR)spectroscopy and differential scanning calorimetry(DSC). Since the IL can form strong hydrogen bonds with water, trace water is a problematic impurity in the IL. Using the standard addition method (SAM), the density, refractive index and surface tension of C4mimLactwere measured in the temperature range(308.15 to 343.15±0.05)K.On the basis of the experimental data, the parachor and molar volume forC4mimLact |
关键词 | NATURAL AMINO-ACIDS SURFACE-TENSION PHYSICOCHEMICAL PROPERTIES PHYSICAL-PROPERTIES TEMPERATURE DENSITY CHLOROALUMINATE POINT parachor lactate ionic liquid density surface tension refractive index |
收录类别 | CSCD |
语种 | 英语 |
资助项目 | [Education Bureau of Liaoning Province] ; [National Natural Science Foundation of China] ; [Liaoning University] |
CSCD记录号 | CSCD:4109352 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/147380 |
专题 | 中国科学院金属研究所 |
作者单位 | 1.中国科学院金属研究所 2.辽宁大学 |
推荐引用方式 GB/T 7714 | Fang DaWei,Tong Jing,Guan Wei,et al. Prediction of the thermodynamic properties of 1-alkyl-3-methylimidazolium lactate ionic liquids C(n)mimLact (n = 2, 3, 4, 5, and 6) by parachor[J]. SCIENCE CHINA-CHEMISTRY,2010,53(12):2564-2570. |
APA | Fang DaWei,Tong Jing,Guan Wei,Wang Han,&Yang JiaZhen.(2010).Prediction of the thermodynamic properties of 1-alkyl-3-methylimidazolium lactate ionic liquids C(n)mimLact (n = 2, 3, 4, 5, and 6) by parachor.SCIENCE CHINA-CHEMISTRY,53(12),2564-2570. |
MLA | Fang DaWei,et al."Prediction of the thermodynamic properties of 1-alkyl-3-methylimidazolium lactate ionic liquids C(n)mimLact (n = 2, 3, 4, 5, and 6) by parachor".SCIENCE CHINA-CHEMISTRY 53.12(2010):2564-2570. |
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