纳米Fe—10Cr涂层电化学腐蚀行为影响研究Ⅱ.点蚀性能 | |
Alternative Title | CORROSION BEHAVIOR OF Fe- 10Cr NANOCRYSTALLINE COATINGS Ⅱ. CORROSION BEHAVIOR OF Fe -10Cr NANOCRYSTALLINE COATINGS IN ACIDIC SOLUTION WITH Cl^- |
孟国哲; 李瑛; 王福会 | |
2007 | |
Source Publication | 中国腐蚀与防护学报
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ISSN | 1005-4537 |
Volume | 27.0Issue:1.0Pages:43-47 |
Abstract | 利用动电位极化曲线、电化学阻抗谱图(EIS)和Mott-Schottky分析等电化学测试手段.探讨了Fe—10Cr纳米涂层在0.05mol/L H2SO4+0.5mol/LNaCl溶液中的腐蚀行为.研究表明,与铸态合金相比,溅射纳米涂层表面钝化膜的化学稳定性和再钝化性能明显提高;二者的钝化膜均具有p型半导体结构特征.但溅射纳米涂层表面钝化膜的载流子密度和平带电位都比较低,导致钝化膜中金属离子的传输速度较低,纳米橡层表面钝化膜的化学稳定性增强。 |
Other Abstract | The corrosion behavior of Fe - 10Cr sputtering coating with nanoscale grain size was investigated in 0.05 mol/L H2SO4 +0.5 mol/L NaCl aqueous solution using polarization curves, EIS and Mott -Schottky analysis. The results indicated that the chemical stability and repassive ability of passive film formed on Fe - 10Cr nc coating was apparently improved. The passive films on both Fe - 10Cr nc coating and cast alloy have p - type semiconducting behavior. The lower acceptor density and flat - band potential of the passive film in comparison with Fe - 10Cr cast alloy lead to the high chemical stability and repassive ability for the passive film on the sputtering coating. |
Keyword | 纳米晶 晶粒尺寸 腐蚀行为 钝化 钝化膜 点蚀 |
Indexed By | CSCD |
Language | 中文 |
CSCD ID | CSCD:2743112 |
Citation statistics |
Cited Times:1[CSCD]
[CSCD Record]
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Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/148111 |
Collection | 中国科学院金属研究所 |
Affiliation | 中国科学院金属研究所 |
Recommended Citation GB/T 7714 | 孟国哲,李瑛,王福会. 纳米Fe—10Cr涂层电化学腐蚀行为影响研究Ⅱ.点蚀性能[J]. 中国腐蚀与防护学报,2007,27.0(1.0):43-47. |
APA | 孟国哲,李瑛,&王福会.(2007).纳米Fe—10Cr涂层电化学腐蚀行为影响研究Ⅱ.点蚀性能.中国腐蚀与防护学报,27.0(1.0),43-47. |
MLA | 孟国哲,et al."纳米Fe—10Cr涂层电化学腐蚀行为影响研究Ⅱ.点蚀性能".中国腐蚀与防护学报 27.0.1.0(2007):43-47. |
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