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Corrosion behavior of ferritic stainless steel with 15wt% chromium for the automobile exhaust system
其他题名Corrosion behavior of ferritic stainless steel with 15wt% chromium for the automobile exhaust system
Li Huabing; Jiang Zhouhua; Feng Hao; Zhu Hongchun; Sun Binhan; Li Zhen
2013
发表期刊INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS
ISSN1674-4799
卷号20期号:9页码:850-860
摘要The effect of chloride ion concentration, pH value, and grain size on the pitting corrosion resistance of a new ferritic stainless steel with 15wt% Cr was investigated using the anodic polarization method. The semiconducting properties of passive films with different chloride ion concentrations were performed using capacitance measurement and Mott-Schottky analysis methods. The aging precipitation and intergranular corrosion behavior were evaluated at 400-900A degrees C. It is found that the pitting potential decreases when the grain size increases. With the increase in chloride ion concentration, the doping density and the flat-bland potential increase but the thickness of the space charge layer decreases. The pitting corrosion resistance increases rapidly with the decrease in pH value. Precipitants is identified as Nb(C,N) and NbC, rather than Cr-carbide. The intergranular corrosion is attributed to the synergistic effects of Nb(C,N) and NbC precipitates and Cr segregation adjacent to the precipitates.
其他摘要The effect of chloride ion concentration, pH value, and grain size on the pitting corrosion resistance of a new ferritic stainless steel with 15wt% Cr was investigated using the anodic polarization method. The semiconducting properties of passive films with different chloride ion concentrations were performed using capacitance measurement and Mott-Schottky analysis methods. The aging precipitation and intergranular corrosion behavior were evaluated at 400–900°C. It is found that the pitting potential decreases when the grain size increases. With the increase in chloride ion concentration, the doping density and the flat-bland potential increase but the thickness of the space charge layer decreases. The pitting corrosion resistance increases rapidly with the decrease in pH value. Precipitants is identified as Nb(C,N) and NbC, rather than Cr-carbide. The intergranular corrosion is attributed to the synergistic effects of Nb(C,N) and NbC precipitates and Cr segregation adjacent to the precipitates.
关键词SEMICONDUCTING PROPERTIES PASSIVE FILM CHLORIDE ferritic stainless steel corrosion resistance pitting chlorides intergranular corrosion grain size
收录类别CSCD
语种英语
资助项目[Program for Liaoning Innovative Research Team in University] ; [Fundamental Research Funds for the Central Universities] ; [General Scientific Research Project of the Department of Education of Liaoning Province, China]
CSCD记录号CSCD:4932755
引用统计
被引频次:4[CSCD]   [CSCD记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/152451
专题中国科学院金属研究所
作者单位中国科学院金属研究所
推荐引用方式
GB/T 7714
Li Huabing,Jiang Zhouhua,Feng Hao,et al. Corrosion behavior of ferritic stainless steel with 15wt% chromium for the automobile exhaust system[J]. INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS,2013,20(9):850-860.
APA Li Huabing,Jiang Zhouhua,Feng Hao,Zhu Hongchun,Sun Binhan,&Li Zhen.(2013).Corrosion behavior of ferritic stainless steel with 15wt% chromium for the automobile exhaust system.INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS,20(9),850-860.
MLA Li Huabing,et al."Corrosion behavior of ferritic stainless steel with 15wt% chromium for the automobile exhaust system".INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS 20.9(2013):850-860.
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