| PREPARATION AND CHARACTERIZATION OF CaB6 BY MOLTEN SALT ELECTROLYSIS | |
| Alternative Title | PREPARATION AND CHARACTERIZATION OF CaB_6 BY MOLTEN SALT ELECTROLYSIS |
| Wang Xu; Zhai Yuchun; Xie Hongwei | |
| 2008 | |
| Source Publication | ACTA METALLURGICA SINICA
 |
| ISSN | 0412-1961 |
| Volume | 44Issue:10Pages:1243-1246 |
| Abstract | CaB6 powder was synthesized by molten salt electrolysis method, and the effects of synthesis temperature, electrolysis voltage and time on the phase composition, particle size and shape of cathode products were analyzed by XRD and SEM. The experimental results show that the best synthesis conditions of CaB6 powder in CaCl2 Molten salt system are: environment of argon, voltage of 3.0 V, temperature of 900 degrees C for 30 h, under which the range of CaB6 crystal size is 2-8 mu m and the morphology of particles is cuboid massive shape. Using cyclic voltammetry in cathode process, it is proved that the electrolysis process is controlled by the diffusion rate of borate to the cathode. |
| Keyword | ELECTROCHEMICAL REDUCTION TITANIUM-DIOXIDE CALCIUM-CHLORIDE EXTRACTION ALLOYS POWDER molten salt electrolysis molten salt system CaB6 diffusion rate cyclic voltammetry |
| Indexed By | CSCD |
| Language | 英语 |
| CSCD ID | CSCD:3420311 |
| Citation statistics |
Cited Times:1[CSCD]
[CSCD Record]
|
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/152815 |
| Collection | 中国科学院金属研究所 |
| Affiliation | 中国科学院金属研究所 |
| Recommended Citation GB/T 7714 | Wang Xu,Zhai Yuchun,Xie Hongwei. PREPARATION AND CHARACTERIZATION OF CaB6 BY MOLTEN SALT ELECTROLYSIS[J]. ACTA METALLURGICA SINICA,2008,44(10):1243-1246. |
| APA | Wang Xu,Zhai Yuchun,&Xie Hongwei.(2008).PREPARATION AND CHARACTERIZATION OF CaB6 BY MOLTEN SALT ELECTROLYSIS.ACTA METALLURGICA SINICA,44(10),1243-1246. |
| MLA | Wang Xu,et al."PREPARATION AND CHARACTERIZATION OF CaB6 BY MOLTEN SALT ELECTROLYSIS".ACTA METALLURGICA SINICA 44.10(2008):1243-1246. |
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