Schiff Base Complex of Gallium: Synthesis and Crystal Structure

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	Schiff Base Complex of Gallium: Synthesis and Crystal Structure
其他题名	Schiff Base Complex of Gallium:Synthesis and Crystal Structure
	Yue Shuang 1; Li Jun 1; Zang ShuLiang 3; Gu XueJun 1; Yu YingJie 3; Jin Hao 1
	2010
发表期刊	CHINESE JOURNAL OF INORGANIC CHEMISTRY
ISSN	1001-4861
卷号	26 期号:5 页码:763-768
摘要	The new Schiff base complexes of gallium GaCl3(C13H11NO) (1), GaCl3 (C14H13NO) (2) and GaCl3(C13H9ClNO) (3) were synthesized under argon atmosphere with the glove box and characterized by elemental analysis, H-1 NMR, IR, and the crystal structures were determined by single-crystal X-ray diffraction. In these complexes, the Ga center is four-coordinate with distorted tetrahedron geometry. The complex 1 crystallizes in an orthorhombic system, the space group Pnma with a=1.329 5(3) nm, b=0.701 15(16) nm, c=1.616 4(4) nm, V=1.506 8(6) nm(3), Z=4, F(000)=744, R-1=0.029 5, wR(2)=0.065 1. And Intermolecular hydrogen bands link the molecules of the complex into two-dimensional network structure. The complex 2 crystallizes in a monoclinic system, the space group P2(1)/n with a=0.713 03(18) nm, b=1.715 3(4) nm, c=1.350 3(4) nm, beta=91.891(5)degrees, V=1.650 7(7) nm(3), Z=4, F(000)=808, R-1=0.044 3, wR(2)=0.098 8. And Intermolecular hydrogen bands link the molecules of the complex into two-dimensional network structure. The complex 3 crystallizes in a triclinic system, the space group P (1) over bar with a=0.698 6(2) nm, b=1.044 9(4) nm, c=1.136 9(3)degrees, alpha=78.58(3)degrees, beta=81.06(2)degrees, gamma=87.87(3)degrees, V=0.803 6(5) nm(3), Z=2, F(000)=402, R-1=0.051 5, wR(2)=0.1244. And Intermolecular hydrogen bands link the molecules of the complex into two-dimensional network structure. CCDC: 649105, 1; 649104, 2; 763895, 3.
关键词	INDIUM COMPLEXES SALICYLALDEHYDE ORGANOALUMINUM ORGANOGALLIUM PRECURSORS LIGANDS Schiff base gallium complex synthesis crystal structure
收录类别	CSCD
语种	英语
CSCD记录号	CSCD:3942611
引用统计
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/154240
专题	中国科学院金属研究所
作者单位	1.中国科学院金属研究所 2.江苏省盐城地震台 3.陕西省地震局
推荐引用方式 GB/T 7714	Yue Shuang,Li Jun,Zang ShuLiang,et al. Schiff Base Complex of Gallium: Synthesis and Crystal Structure[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2010,26(5):763-768.
APA	Yue Shuang,Li Jun,Zang ShuLiang,Gu XueJun,Yu YingJie,&Jin Hao.(2010).Schiff Base Complex of Gallium: Synthesis and Crystal Structure.CHINESE JOURNAL OF INORGANIC CHEMISTRY,26(5),763-768.
MLA	Yue Shuang,et al."Schiff Base Complex of Gallium: Synthesis and Crystal Structure".CHINESE JOURNAL OF INORGANIC CHEMISTRY 26.5(2010):763-768.