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Schiff Base Complex of Gallium: Synthesis and Crystal Structure
Alternative TitleSchiff Base Complex of Gallium:Synthesis and Crystal Structure
Yue Shuang1; Li Jun1; Zang ShuLiang3; Gu XueJun1; Yu YingJie3; Jin Hao1
2010
Source PublicationCHINESE JOURNAL OF INORGANIC CHEMISTRY
ISSN1001-4861
Volume26Issue:5Pages:763-768
AbstractThe new Schiff base complexes of gallium GaCl3(C13H11NO) (1), GaCl3 (C14H13NO) (2) and GaCl3(C13H9ClNO) (3) were synthesized under argon atmosphere with the glove box and characterized by elemental analysis, H-1 NMR, IR, and the crystal structures were determined by single-crystal X-ray diffraction. In these complexes, the Ga center is four-coordinate with distorted tetrahedron geometry. The complex 1 crystallizes in an orthorhombic system, the space group Pnma with a=1.329 5(3) nm, b=0.701 15(16) nm, c=1.616 4(4) nm, V=1.506 8(6) nm(3), Z=4, F(000)=744, R-1=0.029 5, wR(2)=0.065 1. And Intermolecular hydrogen bands link the molecules of the complex into two-dimensional network structure. The complex 2 crystallizes in a monoclinic system, the space group P2(1)/n with a=0.713 03(18) nm, b=1.715 3(4) nm, c=1.350 3(4) nm, beta=91.891(5)degrees, V=1.650 7(7) nm(3), Z=4, F(000)=808, R-1=0.044 3, wR(2)=0.098 8. And Intermolecular hydrogen bands link the molecules of the complex into two-dimensional network structure. The complex 3 crystallizes in a triclinic system, the space group P (1) over bar with a=0.698 6(2) nm, b=1.044 9(4) nm, c=1.136 9(3)degrees, alpha=78.58(3)degrees, beta=81.06(2)degrees, gamma=87.87(3)degrees, V=0.803 6(5) nm(3), Z=2, F(000)=402, R-1=0.051 5, wR(2)=0.1244. And Intermolecular hydrogen bands link the molecules of the complex into two-dimensional network structure. CCDC: 649105, 1; 649104, 2; 763895, 3.
KeywordINDIUM COMPLEXES SALICYLALDEHYDE ORGANOALUMINUM ORGANOGALLIUM PRECURSORS LIGANDS Schiff base gallium complex synthesis crystal structure
Indexed ByCSCD
Language英语
CSCD IDCSCD:3942611
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Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/154240
Collection中国科学院金属研究所
Affiliation1.中国科学院金属研究所
2.江苏省盐城地震台
3.陕西省地震局
Recommended Citation
GB/T 7714
Yue Shuang,Li Jun,Zang ShuLiang,et al. Schiff Base Complex of Gallium: Synthesis and Crystal Structure[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2010,26(5):763-768.
APA Yue Shuang,Li Jun,Zang ShuLiang,Gu XueJun,Yu YingJie,&Jin Hao.(2010).Schiff Base Complex of Gallium: Synthesis and Crystal Structure.CHINESE JOURNAL OF INORGANIC CHEMISTRY,26(5),763-768.
MLA Yue Shuang,et al."Schiff Base Complex of Gallium: Synthesis and Crystal Structure".CHINESE JOURNAL OF INORGANIC CHEMISTRY 26.5(2010):763-768.
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