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Formation of Two-dimensional Metal-water Framework Containing (H2O)(20) Cluster
Alternative TitleFormation of Two-dimensional Metal-water Framework Containing (H_2O)_(20) Cluster
Sun YaGuang1; Ding Fu2; Gu XiaoFu1; Zhang WanZhong1; Wei DeZhou3; Gao EnJun1
2008
Source PublicationCHINESE JOURNAL OF CHEMISTRY
ISSN1001-604X
Volume26Issue:10Pages:1843-1847
AbstractCd(phen)(2)(male)(H2O)center dot 9.5H(2)O (1) has been synthesized by the reaction of Cd(NO3)(2) with phen and male (phen = 1,10-phenanthroline, H(2)male = maleic acid) in a mixture solvent of ethanol and distilled water. The complex was characterized by elemental analysis, infrared spectrum and thermal gravimetric analyses. The crystal structure was determined by X-ray single-crystal diffraction. In 1, a novel 1D water chain containing water (H2O)(20) cluster was formed. Further hydrogen bonding interaction between the water chain and Cd(phen)(2)(male)(H2O) constructs a unique metal-water 2D framework.
Other AbstractCd(phen)_2(male)(H_2O)·9.5H_2O (1) has been synthesized by the reaction of Cd(NO_3)_2 with phen and male (phen=1,10-phenanthroline, H_2male=maleic acid) in a mixture solvent of ethanol and distilled water. The complex was characterized by elemental analysis, infrared spectrum and thermal gravimetric analyses. The crystal structure was determined by X-ray single-crystal diffraction. In 1, a novel 1D water chain containing water (H_2O)_20 cluster was formed. Further hydrogen bonding interaction between the water chain and Cd(phen)_2(male)(H_2O) constructs a unique metal-water 2D framework.
KeywordGRAPH-SET ANALYSIS SUPRAMOLECULAR COMPLEX HEXAMER ICE CRYSTAL CHAIN MORPHOLOGY MOLECULES CHEMISTRY PATTERNS water chemistry supramolecular self-assembly
Indexed ByCSCD
Language英语
Funding Project[National Natural Science Foundation of China] ; [Doctor Foundation of Liaoning Province]
CSCD IDCSCD:3434844
Citation statistics
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/156104
Collection中国科学院金属研究所
Affiliation1.中国科学院金属研究所
2.University Ghent, Dept Inorgan & Phys Chem, B-9000 Ghent, Belgium
3.东北大学
Recommended Citation
GB/T 7714
Sun YaGuang,Ding Fu,Gu XiaoFu,et al. Formation of Two-dimensional Metal-water Framework Containing (H2O)(20) Cluster[J]. CHINESE JOURNAL OF CHEMISTRY,2008,26(10):1843-1847.
APA Sun YaGuang,Ding Fu,Gu XiaoFu,Zhang WanZhong,Wei DeZhou,&Gao EnJun.(2008).Formation of Two-dimensional Metal-water Framework Containing (H2O)(20) Cluster.CHINESE JOURNAL OF CHEMISTRY,26(10),1843-1847.
MLA Sun YaGuang,et al."Formation of Two-dimensional Metal-water Framework Containing (H2O)(20) Cluster".CHINESE JOURNAL OF CHEMISTRY 26.10(2008):1843-1847.
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