Synthesis, Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks Mn(PDC)H2O(n) | |
其他题名 | Synthesis,Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks Mn(PDC)H_2O_n |
EnJun Gao; XiaoFu Gu; YaGuang Sun; HongXi Yin; Qiong Wu; Lei Liu; MingChang Zhu; WanZhong Zhang | |
2008 | |
发表期刊 | CHINESE JOURNAL OF CHEMISTRY
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ISSN | 1001-604X |
卷号 | 26期号:11页码:2133-2136 |
摘要 | A novel coordination polymer, Mn(PDC)H2O(n) (1) (H2PDC=pyridine-2,3-dicarboxylic acid), has been hydrothermally synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction. X-ray single crystal structural analyses revealed that two-dimensional frameworks were formed, and further assembled into a three-dimensional supramolecular Structure bridged by PDC ligands. Moreover, the magnetic study of complex 1 shows weak antiferromagnetic interaction between the neighboring Mn(II) centers within the chains and even weak ferromagnetic interactions between the Mn(II) centers in different chains. |
其他摘要 | A novel coordination polymer,Mn(PDC)H_2O_n(1)(H_2PDC=pyridine-2,3-dicarboxylic acid),has been hydrothermally synthesized and characterized by elemental analysis,IR and single crystal X-ray diffraction.X-ray single crystal structural analyses revealed that two-dimensional frameworks were formed,and further assembled into a three-dimensional supramolecular structure bridged by PDC ligands.Moreover,the magnetic study of complex 1 shows weak antiferromagnetic interaction between the neighboring Mn(Ⅱ)centers within the chains and even weak ferromagnetic interactions between the Mn(Ⅱ)centers in different chains. |
关键词 | COORDINATION POLYMERS manganese(II) coordination polymer crystal structure magnetic property |
收录类别 | CSCD |
语种 | 英语 |
资助项目 | [Natural Science Foundation of Liaoning Province] ; [Educational Department Foundation of Liaoning Province] |
CSCD记录号 | CSCD:3585784 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/156119 |
专题 | 中国科学院金属研究所 |
作者单位 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | EnJun Gao,XiaoFu Gu,YaGuang Sun,et al. Synthesis, Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks Mn(PDC)H2O(n)[J]. CHINESE JOURNAL OF CHEMISTRY,2008,26(11):2133-2136. |
APA | EnJun Gao.,XiaoFu Gu.,YaGuang Sun.,HongXi Yin.,Qiong Wu.,...&WanZhong Zhang.(2008).Synthesis, Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks Mn(PDC)H2O(n).CHINESE JOURNAL OF CHEMISTRY,26(11),2133-2136. |
MLA | EnJun Gao,et al."Synthesis, Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks Mn(PDC)H2O(n)".CHINESE JOURNAL OF CHEMISTRY 26.11(2008):2133-2136. |
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