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Synthesis, Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks Mn(PDC)H2O(n)
其他题名Synthesis,Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks Mn(PDC)H_2O_n
EnJun Gao; XiaoFu Gu; YaGuang Sun; HongXi Yin; Qiong Wu; Lei Liu; MingChang Zhu; WanZhong Zhang
2008
发表期刊CHINESE JOURNAL OF CHEMISTRY
ISSN1001-604X
卷号26期号:11页码:2133-2136
摘要A novel coordination polymer, Mn(PDC)H2O(n) (1) (H2PDC=pyridine-2,3-dicarboxylic acid), has been hydrothermally synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction. X-ray single crystal structural analyses revealed that two-dimensional frameworks were formed, and further assembled into a three-dimensional supramolecular Structure bridged by PDC ligands. Moreover, the magnetic study of complex 1 shows weak antiferromagnetic interaction between the neighboring Mn(II) centers within the chains and even weak ferromagnetic interactions between the Mn(II) centers in different chains.
其他摘要A novel coordination polymer,Mn(PDC)H_2O_n(1)(H_2PDC=pyridine-2,3-dicarboxylic acid),has been hydrothermally synthesized and characterized by elemental analysis,IR and single crystal X-ray diffraction.X-ray single crystal structural analyses revealed that two-dimensional frameworks were formed,and further assembled into a three-dimensional supramolecular structure bridged by PDC ligands.Moreover,the magnetic study of complex 1 shows weak antiferromagnetic interaction between the neighboring Mn(Ⅱ)centers within the chains and even weak ferromagnetic interactions between the Mn(Ⅱ)centers in different chains.
关键词COORDINATION POLYMERS manganese(II) coordination polymer crystal structure magnetic property
收录类别CSCD
语种英语
资助项目[Natural Science Foundation of Liaoning Province] ; [Educational Department Foundation of Liaoning Province]
CSCD记录号CSCD:3585784
引用统计
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/156119
专题中国科学院金属研究所
作者单位中国科学院金属研究所
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GB/T 7714
EnJun Gao,XiaoFu Gu,YaGuang Sun,et al. Synthesis, Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks Mn(PDC)H2O(n)[J]. CHINESE JOURNAL OF CHEMISTRY,2008,26(11):2133-2136.
APA EnJun Gao.,XiaoFu Gu.,YaGuang Sun.,HongXi Yin.,Qiong Wu.,...&WanZhong Zhang.(2008).Synthesis, Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks Mn(PDC)H2O(n).CHINESE JOURNAL OF CHEMISTRY,26(11),2133-2136.
MLA EnJun Gao,et al."Synthesis, Crystal Structure and Magnetic Properties of Novel Three-dimensional Frameworks Mn(PDC)H2O(n)".CHINESE JOURNAL OF CHEMISTRY 26.11(2008):2133-2136.
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