| Synthesis and Crystal Structure of a 1-D Chain Coordination Complex {Mn2（HCAM）3（H2bipy）·5H2O}n | |
| Alternative Title | Synthesis and Crystal Structure of a 1-D Chain Coordination Complex {Mn2（HCAM）3（H2bipy）·5H2O}n |
| SUN YaGuang; RONG ShuTing; WU YongLi; YU Wan; WANG ChuanSheng; ZHANO WanZhong; GAO EnJun | |
| 2009 | |
| Source Publication | 结构化学
 |
| ISSN | 0254-5861 |
| Volume | 28.0Issue:009Pages:1131-1135 |
| Abstract | The 1-D chain coordination complex of {Mn2（HCAM）3（H2bipy）·5H2O}n （H3CAM = 4-hydroxypyridine-2,6-dicarboxylic acid, bipy = 4,4＇-bipyridine） has been synthesized by the reaction of 4-hydroxypyridine-2,6-dicarboxylic acid, 4,4＇-bipyridine and manganese carbonate under hydrothermal conditions, and its crystal structure was determined by X-ray diffraction method The crystal belongs to the monoclinic system, space group P21/n with a = 10.110（2）, b = 20.159（4）, c = 17.861（4）A,β = 99.67（3）°, V = 3.5884（12） nm3, Mr= 901.47, Z = 4, Dc= 1.669 g.cm^-3, μ= 0.798 mm^-1, F（000） = 1840, the final R = 0.0713 and ωR = 0.1853. The complex forms a 1-D chain bridged by HCAM, protonated 4,4-bipyridines link the 1-D chains to construct 2-D networks via N-H...O hydrogen bonds, and networks are further extended via π-π stacking and hydrogen bonds into 3-D supramolecular framework. |
| Other Abstract | The 1-D chain coordination complex of {Mn2（HCAM）3（H2bipy）·5H2O}n （H3CAM = 4-hydroxypyridine-2,6-dicarboxylic acid, bipy = 4,4＇-bipyridine） has been synthesized by the reaction of 4-hydroxypyridine-2,6-dicarboxylic acid, 4,4＇-bipyridine and manganese carbonate under hydrothermal conditions, and its crystal structure was determined by X-ray diffraction method The crystal belongs to the monoclinic system, space group P21/n with a = 10.110（2）, b = 20.159（4）, c = 17.861（4）A,β = 99.67（3）°, V = 3.5884（12） nm3, Mr= 901.47, Z = 4, Dc= 1.669 g.cm^-3, μ= 0.798 mm^-1, F（000） = 1840, the final R = 0.0713 and ωR = 0.1853. The complex forms a 1-D chain bridged by HCAM, protonated 4,4-bipyridines link the 1-D chains to construct 2-D networks via N-H...O hydrogen bonds, and networks are further extended via π-π stacking and hydrogen bonds into 3-D supramolecular framework. |
| Keyword | 晶体结构 一维链 配合物 合成 锰 协调 X射线衍射法 联吡啶 |
| Indexed By | CSCD |
| Language | 中文 |
| CSCD ID | CSCD:3668506 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/157193 |
| Collection | 中国科学院金属研究所 |
| Affiliation | 中国科学院金属研究所 |
| Recommended Citation GB/T 7714 | SUN YaGuang,RONG ShuTing,WU YongLi,等. Synthesis and Crystal Structure of a 1-D Chain Coordination Complex {Mn2（HCAM）3（H2bipy）·5H2O}n[J]. 结构化学,2009,28.0(009):1131-1135. |
| APA | SUN YaGuang.,RONG ShuTing.,WU YongLi.,YU Wan.,WANG ChuanSheng.,...&GAO EnJun.(2009).Synthesis and Crystal Structure of a 1-D Chain Coordination Complex {Mn2（HCAM）3（H2bipy）·5H2O}n.结构化学,28.0(009),1131-1135. |
| MLA | SUN YaGuang,et al."Synthesis and Crystal Structure of a 1-D Chain Coordination Complex {Mn2（HCAM）3（H2bipy）·5H2O}n".结构化学 28.0.009(2009):1131-1135. |
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