IMR OpenIR
Synthesis and Crystal Structure of Complex Pb(qina)2(DMSO)·H2O
Alternative TitleSynthesis and Crystal Structure of Complex Pb(qina)2(DMSO)·H2O
ZHANG WanZhong1; WEI DeZhou1; GAO EnJun2; SUN YaGuang2
2007
Source Publication结构化学
ISSN0254-5861
Volume26.0Issue:003Pages:357-360
AbstractA novel complex Pb(qina)2(DMSO)·H2O was synthesized, of which qinais the quinaldic acid radical and DMSO the dimethyl sulfoxide. Elemental analysis, IR spectra, and X-ray single-crystal diffraction were carried out to determine the composition and crystal structure. This complex belongs to monoclinic system, space group P121/n1, with a = 7.1553(17), b = 17.543(2), c = 17.306(2) A, β = 91.671(4)°, C22H20N206PbS, Mr = 647.65, Z = 4, V= 2171.5(6) A3, Dc= 1.981 g/cm^3, μ= 7.908 mm^-1, F(000) = 1248, -9≤h≤6, -23≤k≤19, -22≤1≤22, R= 0.0221 and wR= 0.0488. Weak coordinate bond is formed between oxygen atom in DMSO and Pb( Ⅱ ). There are also weak interactions, such as π-π interaction, hydrogen bonds and so on, among the complex molecules.
Other AbstractA novel complex Pb(qina)2(DMSO)·H2O was synthesized, of which qinais the quinaldic acid radical and DMSO the dimethyl sulfoxide. Elemental analysis, IR spectra, and X-ray single-crystal diffraction were carried out to determine the composition and crystal structure. This complex belongs to monoclinic system, space group P121/n1, with a = 7.1553(17), b = 17.543(2), c = 17.306(2) A, β = 91.671(4)°, C22H20N206PbS, Mr = 647.65, Z = 4, V= 2171.5(6) A3, Dc= 1.981 g/cm^3, μ= 7.908 mm^-1, F(000) = 1248, -9≤h≤6, -23≤k≤19, -22≤1≤22, R= 0.0221 and wR= 0.0488. Weak coordinate bond is formed between oxygen atom in DMSO and Pb( Ⅱ ). There are also weak interactions, such as π-π interaction, hydrogen bonds and so on, among the complex molecules.
Keyword铅配合物 喹拿啶酸 DMSO 合成 晶体结构
Indexed ByCSCD
Language中文
CSCD IDCSCD:2729858
Citation statistics
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/157814
Collection中国科学院金属研究所
Affiliation1.东北大学
2.中国科学院金属研究所
Recommended Citation
GB/T 7714
ZHANG WanZhong,WEI DeZhou,GAO EnJun,等. Synthesis and Crystal Structure of Complex Pb(qina)2(DMSO)·H2O[J]. 结构化学,2007,26.0(003):357-360.
APA ZHANG WanZhong,WEI DeZhou,GAO EnJun,&SUN YaGuang.(2007).Synthesis and Crystal Structure of Complex Pb(qina)2(DMSO)·H2O.结构化学,26.0(003),357-360.
MLA ZHANG WanZhong,et al."Synthesis and Crystal Structure of Complex Pb(qina)2(DMSO)·H2O".结构化学 26.0.003(2007):357-360.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[ZHANG WanZhong]'s Articles
[WEI DeZhou]'s Articles
[GAO EnJun]'s Articles
Baidu academic
Similar articles in Baidu academic
[ZHANG WanZhong]'s Articles
[WEI DeZhou]'s Articles
[GAO EnJun]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[ZHANG WanZhong]'s Articles
[WEI DeZhou]'s Articles
[GAO EnJun]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.