Synthesis and Crystal Structure of Complex Pb（qina）2（DMSO）·H2O

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	Synthesis and Crystal Structure of Complex Pb（qina）2（DMSO）·H2O
其他题名	Synthesis and Crystal Structure of Complex Pb（qina）2（DMSO）·H2O
	ZHANG WanZhong 1; WEI DeZhou 1; GAO EnJun 2; SUN YaGuang 2
	2007
发表期刊	结构化学
ISSN	0254-5861
卷号	26.0 期号:003 页码:357-360
摘要	A novel complex Pb（qina）2（DMSO）·H2O was synthesized, of which qinais the quinaldic acid radical and DMSO the dimethyl sulfoxide. Elemental analysis, IR spectra, and X-ray single-crystal diffraction were carried out to determine the composition and crystal structure. This complex belongs to monoclinic system, space group P121/n1, with a = 7.1553（17）, b = 17.543（2）, c = 17.306（2） A, β = 91.671（4）°, C22H20N206PbS, Mr = 647.65, Z = 4, V= 2171.5（6） A3, Dc= 1.981 g/cm^3, μ= 7.908 mm^-1, F（000） = 1248, -9≤h≤6, -23≤k≤19, -22≤1≤22, R= 0.0221 and wR= 0.0488. Weak coordinate bond is formed between oxygen atom in DMSO and Pb（ Ⅱ ）. There are also weak interactions, such as π-π interaction, hydrogen bonds and so on, among the complex molecules.
其他摘要	A novel complex Pb（qina）2（DMSO）·H2O was synthesized, of which qinais the quinaldic acid radical and DMSO the dimethyl sulfoxide. Elemental analysis, IR spectra, and X-ray single-crystal diffraction were carried out to determine the composition and crystal structure. This complex belongs to monoclinic system, space group P121/n1, with a = 7.1553（17）, b = 17.543（2）, c = 17.306（2） A, β = 91.671（4）°, C22H20N206PbS, Mr = 647.65, Z = 4, V= 2171.5（6） A3, Dc= 1.981 g/cm^3, μ= 7.908 mm^-1, F（000） = 1248, -9≤h≤6, -23≤k≤19, -22≤1≤22, R= 0.0221 and wR= 0.0488. Weak coordinate bond is formed between oxygen atom in DMSO and Pb（ Ⅱ ）. There are also weak interactions, such as π-π interaction, hydrogen bonds and so on, among the complex molecules.
关键词	铅配合物喹拿啶酸 DMSO 合成晶体结构
收录类别	CSCD
语种	中文
CSCD记录号	CSCD:2729858
引用统计
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/157814
专题	中国科学院金属研究所
作者单位	1.东北大学 2.中国科学院金属研究所
推荐引用方式 GB/T 7714	ZHANG WanZhong,WEI DeZhou,GAO EnJun,等. Synthesis and Crystal Structure of Complex Pb（qina）2（DMSO）·H2O[J]. 结构化学,2007,26.0(003):357-360.
APA	ZHANG WanZhong,WEI DeZhou,GAO EnJun,&SUN YaGuang.(2007).Synthesis and Crystal Structure of Complex Pb（qina）2（DMSO）·H2O.结构化学,26.0(003),357-360.
MLA	ZHANG WanZhong,et al."Synthesis and Crystal Structure of Complex Pb（qina）2（DMSO）·H2O".结构化学 26.0.003(2007):357-360.