Synthesis strategies towards amorphous porous carbons with selective oxygen functionalization for the application as reference material

doi:10.1016/j.carbon.2020.09.030

IMR OpenIR

	Synthesis strategies towards amorphous porous carbons with selective oxygen functionalization for the application as reference material
	Herold, Felix 1; Leubner, Oliver 1; Pfeifer, Philipp 1; Zakgeym, Dina 2; Drochner, Alfons 1; Qi, Wei 3; Etzold, Bastian J. M.1
通讯作者	Etzold, Bastian J. M.(bastian.etzold@tu-darmstadt.de)
	2021
发表期刊	CARBON
ISSN	0008-6223
卷号	171 页码:658-670
摘要	Manipulation of carbon surface functionalization and especially of oxygen surface groups has been demonstrated to be key for obtaining high performance materials in a multitude of applications. Although control of carbon surface chemistry offers large potential in many technical relevant applications, qualitative and quantitative analysis of surface oxides for amorphous and porous carbons remains challenging. In this study, we attempt selective, organic chemistry-based functionalization of a polymer-derived porous model carbon featuring high oxygen loadings, with the aim to establish analytical standards for temperature programmed desorption (TPD) and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). In this context, quantitative chemical reduction of an oxidized carbon material with lithium aluminum hydride (LiAlH4) is utilized as the key for the synthesis of carbon materials with defined ensembles of oxygen surface groups (hydroxyl groups and ethers). Based on this reduction strategy, selective LiAlH4 reduction based on protection group chemistry leads to aldehydes, ketones and quinones as surface functional groups and chemical grafting is studied for the selective introduction of phenyl esters, methyl ethers and carboxylic acids. All materials are evaluated with respect to the applicability as analytical standard by DRIFT spectroscopy, TPD, X-ray photoelectron spectroscopy and titration methods. (C) 2020 Elsevier Ltd. All rights reserved.
关键词	Oxygen surface groups on carbon Selective surface functionalization TPD DRIFTS
资助者	Deutsche Bundesstiftung Umwelt (DBU) ; Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) ; NSFC of China ; Natural Science Foundation of Liaoning Province of China
DOI	10.1016/j.carbon.2020.09.030
收录类别	SCI
语种	英语
资助项目	Deutsche Bundesstiftung Umwelt (DBU) ; Deutsche Forschungsgemeinschaft (DFG, German Research Foundation)[ET-101/131] ; NSFC of China[21761132010] ; Natural Science Foundation of Liaoning Province of China[2020-YQ-02]
WOS研究方向	Chemistry ; Materials Science
WOS类目	Chemistry, Physical ; Materials Science, Multidisciplinary
WOS记录号	WOS:000598371500069
出版者	PERGAMON-ELSEVIER SCIENCE LTD
引用统计	被引频次：13[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/158833
专题	中国科学院金属研究所
通讯作者	Etzold, Bastian J. M.
作者单位	1.Tech Univ Darmstadt, Dept Chem, Ernst Berl Inst Tech & Makromol Chem, D-64287 Darmstadt, Germany 2.Forschungszentrum Julich, Helmholtz Inst Erlangen Nurnberg Renewable Energy, Egerlandstr 3, D-91058 Erlangen, Germany 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Herold, Felix,Leubner, Oliver,Pfeifer, Philipp,et al. Synthesis strategies towards amorphous porous carbons with selective oxygen functionalization for the application as reference material[J]. CARBON,2021,171:658-670.
APA	Herold, Felix.,Leubner, Oliver.,Pfeifer, Philipp.,Zakgeym, Dina.,Drochner, Alfons.,...&Etzold, Bastian J. M..(2021).Synthesis strategies towards amorphous porous carbons with selective oxygen functionalization for the application as reference material.CARBON,171,658-670.
MLA	Herold, Felix,et al."Synthesis strategies towards amorphous porous carbons with selective oxygen functionalization for the application as reference material".CARBON 171(2021):658-670.