Effect of pH and NaF addition on corrosion of Zr-based bulk metallic glass in Na2SO4-containing solution

doi:10.1016/j.intermet.2020.107034

IMR OpenIR

	Effect of pH and NaF addition on corrosion of Zr-based bulk metallic glass in Na2SO4-containing solution
	Qiu, Zhang-wei-jia 1,2; Li, Zheng-kun 2; Fu, Hua-meng 2,3; Zhang, Long 2; Zhu, Zheng-wang 2,3; Zhang, Hong-wei 2; Wang, Ai-min 2,3; Li, Hong 2; Zhang, Hai-feng 2,3
通讯作者	Fu, Hua-meng(hmfu@imr.ac.cn) ; Zhang, Hai-feng(hfzhang@imr.ac.cn)
	2021-02-01
发表期刊	INTERMETALLICS
ISSN	0966-9795
卷号	129 页码:12
摘要	In order to expand the application of Zr-based bulk metallic glasses (BMGs) in the field of biomaterials, it is vital to investigate their corrosion behaviour in different solution environments. However, until now, the corrosion behaviour of Zr-based BMGs in F--containing solution has been rarely studied, and the corrosion mechanism is not fully understood. In this study, the effect of pH and NaF addition on the corrosion behaviour of Zr52Al10Ni6Cu32 BMG in Na2SO4-containing solution has been investigated by employing the standard electrochemical methods. The relationship between the critical pF value and pH has been subsequently obtained, which provides a criterion for judging the state of corrosion of Zr-based BMGs in F--containing solution. The cathodic reaction mainly involves the reduction of the dissolved oxygen in the solution, and the kinetic mechanism is similar to that of pure Zr. An oxidation peak appearing during the upward polarization scanning is attributed to the active dissolution of Cu caused by SO42- and F-. During upward polarization, different pH values and addition of NaF are observed to result in consequent film breakdown behaviour. For 0.1 M NaF and pH = 8.0, the protective ZrO2 passive film is noted to be replaced by the corrosion product of the Zr-F compound. However, at pH = 4.0 with 0.001 M NaF, the F- concentration is not sufficient to form the Zr-F corrosion products, and the dissolution rate of the passive film is enhanced due to the reduced pH. This study provides a deeper understanding of the corrosion mechanism of Zr-based BMGs alloys in F--containing solution.
关键词	Metallic glass Zirconium Corrosion behaviour NaF Passivation
资助者	National Key Research and Development Program of China ; National Natural Science Foundation of China ; Liaoning Revitalization Talents Program ; Chinese Academy of Sciences ; DongGuan Innovative Research Team Program ; fund of Shenyang National Laboratory for Materials Science ; Ji Hua Laboratory in Foshan, China
DOI	10.1016/j.intermet.2020.107034
收录类别	SCI
语种	英语
资助项目	National Key Research and Development Program of China[2018YFB0703402] ; National Natural Science Foundation of China[51790484] ; National Natural Science Foundation of China[51801209] ; Liaoning Revitalization Talents Program[XLYC1802078] ; Liaoning Revitalization Talents Program[XLYC1807062] ; Chinese Academy of Sciences[ZDBS-LY-JSC023] ; DongGuan Innovative Research Team Program[2014607134] ; fund of Shenyang National Laboratory for Materials Science[L2019F41] ; Ji Hua Laboratory in Foshan, China
WOS研究方向	Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目	Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号	WOS:000604534900004
出版者	ELSEVIER SCI LTD
引用统计	被引频次：2[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/158891
专题	中国科学院金属研究所
通讯作者	Fu, Hua-meng; Zhang, Hai-feng
作者单位	1.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 3.Dongguan Eontec Co Ltd, Dongguan 523662, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Qiu, Zhang-wei-jia,Li, Zheng-kun,Fu, Hua-meng,et al. Effect of pH and NaF addition on corrosion of Zr-based bulk metallic glass in Na2SO4-containing solution[J]. INTERMETALLICS,2021,129:12.
APA	Qiu, Zhang-wei-jia.,Li, Zheng-kun.,Fu, Hua-meng.,Zhang, Long.,Zhu, Zheng-wang.,...&Zhang, Hai-feng.(2021).Effect of pH and NaF addition on corrosion of Zr-based bulk metallic glass in Na2SO4-containing solution.INTERMETALLICS,129,12.
MLA	Qiu, Zhang-wei-jia,et al."Effect of pH and NaF addition on corrosion of Zr-based bulk metallic glass in Na2SO4-containing solution".INTERMETALLICS 129(2021):12.