Nanoscale Hybrid Amorphous/Graphitic Carbon as Key Towards Next-Generation Carbon-Based Oxidative Dehydrogenation Catalysts

doi:10.1002/anie.202014862

IMR OpenIR

	Nanoscale Hybrid Amorphous/Graphitic Carbon as Key Towards Next-Generation Carbon-Based Oxidative Dehydrogenation Catalysts
	Herold, Felix 1; Prosch, Stefan 1; Oefner, Niklas 1; Brunnengraeber, Kai 1; Leubner, Oliver 1; Hermans, Yannick 2; Hofmann, Kathrin 3; Drochner, Alfons 1; Hofmann, Jan P.2; Qi, Wei 4; Etzold, Bastian J. M.1
通讯作者	Etzold, Bastian J. M.(bastian.etzold@tu-darmstadt.de)
	2021-01-26
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN	1433-7851
页码	10
摘要	A new strategy affords "non-nano" carbon materials as dehydrogenation catalysts that perform similarly to nanocarbons. Polymer-based carbon precursors that combine a soft-template approach with ion adsorption and catalytic graphitization are key to this synthesis strategy, thus offering control over macroscopic shape, texture, and crystallinity and resulting in a hybrid amorphous/graphitic carbon after pyrolysis. From this intermediate the active carbon catalyst is prepared by removing the amorphous parts of the hybrid carbon materials via selective oxidation. The oxidative dehydrogenation of ethanol was chosen as test reaction, which shows that fine-tuning the synthesis of the new carbon catalysts allows to obtain a catalytic material with an attractive high selectivity (82 %) similar to a carbon nanotube reference, while achieving 10 times higher space-time yields at 330 degrees C. This new class of carbon materials is accessible via a technically scalable, reproducible synthetic pathway and exhibits spherical particles with diameters around 100 mu m, allowing unproblematic handling similar to classic non-nano catalysts.
关键词	carbon materials heterogeneous catalysis oxidative dehydrogenation
资助者	Deutsche Bundesstiftung Umwelt (DBU) ; Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) ; European Research Council (ERC) under the European Union ; NSFC of China ; Natural Science Foundation of Liaoning Province of China ; Projekt DEAL
DOI	10.1002/anie.202014862
收录类别	SCI
语种	英语
资助项目	Deutsche Bundesstiftung Umwelt (DBU) ; Deutsche Forschungsgemeinschaft (DFG, German Research Foundation)[ET-101/13-1] ; European Research Council (ERC) under the European Union[681719] ; NSFC of China[22072163] ; NSFC of China[21761132010] ; Natural Science Foundation of Liaoning Province of China[2020-YQ-02] ; Projekt DEAL
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000611658600001
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：38[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/159100
专题	中国科学院金属研究所
通讯作者	Etzold, Bastian J. M.
作者单位	1.Tech Univ Darmstadt, Dept Chem, Ernst Berl Inst Tech & Makromol Chem, Alarich Weiss Str 8, D-64287 Darmstadt, Germany 2.Tech Univ Darmstadt, Surface Sci Lab, Dept Mat & Earth Sci, Otto Berndt Str 3, D-64287 Darmstadt, Germany 3.Tech Univ Darmstadt, Dept Chem, Eduard Zintl Inst Anorgan & Phys Chem, Alarich Weiss Str 12, D-64287 Darmstadt, Germany 4.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Wenhua Rd 72, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Herold, Felix,Prosch, Stefan,Oefner, Niklas,et al. Nanoscale Hybrid Amorphous/Graphitic Carbon as Key Towards Next-Generation Carbon-Based Oxidative Dehydrogenation Catalysts[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2021:10.
APA	Herold, Felix.,Prosch, Stefan.,Oefner, Niklas.,Brunnengraeber, Kai.,Leubner, Oliver.,...&Etzold, Bastian J. M..(2021).Nanoscale Hybrid Amorphous/Graphitic Carbon as Key Towards Next-Generation Carbon-Based Oxidative Dehydrogenation Catalysts.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,10.
MLA	Herold, Felix,et al."Nanoscale Hybrid Amorphous/Graphitic Carbon as Key Towards Next-Generation Carbon-Based Oxidative Dehydrogenation Catalysts".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021):10.