Identification of the Reduction Reaction Mechanism of V3+ on a Graphite Electrode in Acidic Solutions

doi:10.1149/1945-7111/abd36d

IMR OpenIR

	Identification of the Reduction Reaction Mechanism of V3+ on a Graphite Electrode in Acidic Solutions
	Jing, Minghua 1,2; Fang, Dawei 2; Fan, Xinzhuang 1,3; Liu, Jianguo 1; Yan, Chuanwei 1
通讯作者	Fan, Xinzhuang(mexzfan@gmail.com)
	2020-12-01
发表期刊	JOURNAL OF THE ELECTROCHEMICAL SOCIETY
ISSN	0013-4651
卷号	167 期号:16 页码:6
摘要	The oxidation and reduction reaction mechanisms of the VO2+/VO2+ redox couple have been studied to better understand the electrode reaction processes and further optimize the battery performance of vanadium flow battery (VFB) in our previous work. However, it is found that the negative electrode process of VFB plays a more important role in the improvement of the overall battery performance as research continues. Hence, the reduction reaction mechanism of V3+ in acidic solutions has been investigated systematacially in this work. Potentiodynamic polarization combined with rotating disk electrode have been applied to calculate the reaction orders (m) and the electron transfer number (n) of the reduction reaction of V3+. The results of this work demonstrated that the reduction reaction of V3+ is a single electron transfer step and H+ keeps out of the electrochemical reaction. Furthermore, the kinetic equation for the reduction reaction of V3+ has been established, and the theoretic polarization curve based on the established kinetic equation is well consistent with the experimental result, indicating an accurate prediction of the polarization behavior in V3+ acidic solutions.
关键词	Energy Storage Batteries aqueous Electrode Kinetics
资助者	Natural Science Foundation of China ; Open project of State Key Laboratory of Heavy Oil Processing in China University of Petroleum ; Science and Technology Seedling Project of Liaoning Provincial education department ; Youth Research Fund of Liaoning University ; Doctoral Fund of Liaoning Provincial Department of Science and Technology
DOI	10.1149/1945-7111/abd36d
收录类别	SCI
语种	英语
资助项目	Natural Science Foundation of China[21703263] ; Open project of State Key Laboratory of Heavy Oil Processing in China University of Petroleum[Y7F1911191] ; Science and Technology Seedling Project of Liaoning Provincial education department[LQN201911] ; Youth Research Fund of Liaoning University[LDQN2019019] ; Doctoral Fund of Liaoning Provincial Department of Science and Technology[2020-BS-079]
WOS研究方向	Electrochemistry ; Materials Science
WOS类目	Electrochemistry ; Materials Science, Coatings & Films
WOS记录号	WOS:000615207900001
出版者	ELECTROCHEMICAL SOC INC
引用统计	被引频次：4[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/159139
专题	中国科学院金属研究所
通讯作者	Fan, Xinzhuang
作者单位	1.Chinese Acad Sci, Inst Met Res, Liaoning Engn Res Ctr Adv Battery Mat, Shenyang 110016, Peoples R China 2.Liaoning Univ, Inst Rare & Scattered Elements, Coll Chem, Shenyang 110036, Peoples R China 3.Guangzhou HKUST Fok Ying Tung Res Inst, Bldg Energy Res Ctr, Guangzhou 511458, Peoples R China
推荐引用方式 GB/T 7714	Jing, Minghua,Fang, Dawei,Fan, Xinzhuang,et al. Identification of the Reduction Reaction Mechanism of V3+ on a Graphite Electrode in Acidic Solutions[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,2020,167(16):6.
APA	Jing, Minghua,Fang, Dawei,Fan, Xinzhuang,Liu, Jianguo,&Yan, Chuanwei.(2020).Identification of the Reduction Reaction Mechanism of V3+ on a Graphite Electrode in Acidic Solutions.JOURNAL OF THE ELECTROCHEMICAL SOCIETY,167(16),6.
MLA	Jing, Minghua,et al."Identification of the Reduction Reaction Mechanism of V3+ on a Graphite Electrode in Acidic Solutions".JOURNAL OF THE ELECTROCHEMICAL SOCIETY 167.16(2020):6.