A hydrogen bond based self-healing superhydrophobic octadecyltriethoxysilane-lignocellulose/silica coating

doi:10.1016/j.porgcoat.2020.106104

IMR OpenIR

	A hydrogen bond based self-healing superhydrophobic octadecyltriethoxysilane-lignocellulose/silica coating
	Bai, Zeng-Guo 1; Bai, Yao-Yao 1; Zhang, Guang-Ping 2; Wang, Si-Qi 1; Zhang, Bin 1
通讯作者	Zhang, Bin(zhangb@atm.neu.edu.cn)
	2021-02-01
发表期刊	PROGRESS IN ORGANIC COATINGS
ISSN	0300-9440
卷号	151 页码:10
摘要	Traditionally, an external stimulus is necessary for a self-healing superhydrophobic coating to achieve self repairing after physical or chemical damage, and this requirement seriously restricts the practical applications of such coatings. Fortunately, a superhydrophobic paint was fabricated successfully in present work. The paint was composed of lignocellulose (LC) and silica (SiO2) with hydroxyl-enriched surfaces coupled with octadecyltriethoxysilane (OTS) via hydrogen bonds, epoxy, and polyamide resin as binders. The paint can be applied to aluminum, glass, fabric, and many other substrates. The coated substrates were further modified with OTS to obtain self-healing superhydrophobic coatings. Only 4 h were needed for the coating to restore the original chemical composition and superhydrophobicity at room temperature after it was chemically damaged. The hydrogen bonds between LC/SiO2-OH and OTS-OH provided the efficient, spontaneous, and repeatable self healing capability for the coating. The coating possessed excellent chemical resistance and withstood 12 h of corrosion in strong acidic and alkaline solutions. Meanwhile, the coating demonstrated outstanding mechanical stability and maintained its superhydrophobic character after 5 h of water jetting (40 kPa). Also, the coated fabric could also be used for reutilized oil-water separation.
关键词	Hydrogen bonds Self-healing Superhydrophobic Mechanical stability Oil-water separation
资助者	National Natural Science Foundation of China (NSFC)
DOI	10.1016/j.porgcoat.2020.106104
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China (NSFC)[51671050] ; National Natural Science Foundation of China (NSFC)[51971060]
WOS研究方向	Chemistry ; Materials Science
WOS类目	Chemistry, Applied ; Materials Science, Coatings & Films
WOS记录号	WOS:000613591500006
出版者	ELSEVIER SCIENCE SA
引用统计	被引频次：28[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/159193
专题	中国科学院金属研究所
通讯作者	Zhang, Bin
作者单位	1.Northeastern Univ, Sch Mat Sci & Engn, Key Lab Anisotropy & Texture Mat, Minist Educ, 3-11 Wenhua Rd, Shenyang 110819, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Bai, Zeng-Guo,Bai, Yao-Yao,Zhang, Guang-Ping,et al. A hydrogen bond based self-healing superhydrophobic octadecyltriethoxysilane-lignocellulose/silica coating[J]. PROGRESS IN ORGANIC COATINGS,2021,151:10.
APA	Bai, Zeng-Guo,Bai, Yao-Yao,Zhang, Guang-Ping,Wang, Si-Qi,&Zhang, Bin.(2021).A hydrogen bond based self-healing superhydrophobic octadecyltriethoxysilane-lignocellulose/silica coating.PROGRESS IN ORGANIC COATINGS,151,10.
MLA	Bai, Zeng-Guo,et al."A hydrogen bond based self-healing superhydrophobic octadecyltriethoxysilane-lignocellulose/silica coating".PROGRESS IN ORGANIC COATINGS 151(2021):10.