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Controllable electronic effect via deep eutectic solvents modification for boosted aerobic oxidative desulfurization
Lu, Linjie1; Zhang, Bingsen2; Li, Hongping1; Chao, Yanhong3; Li, Yujun1; Chen, Linlin1; Li, Huaming1; Ji, Hongbing1,4; Wu, Peiwen1; Zhu, Wenshuai1
Corresponding AuthorZhu, Wenshuai(zhuws@ujs.edu.cn)
2021-08-01
Source PublicationMOLECULAR CATALYSIS
ISSN2468-8231
Volume512Pages:8
AbstractTuning electronic structure of metal catalysts by organic modification is an efficient strategy for domination of their catalytic performances. However, the electronic structure tuning over metal-free catalysts remains to be a challenge. In this work, an organic modification strategy with deep eutectic solvents (DES) as organic modifier over metal-free catalysts was proposed to tune the electronic structure of hexagonal boron nitride (h-BN). Detailed experiments showed that the electronic properties of h-BN was rationally tuned by the introduced DES, in which the B atoms in h-BN were positively charged. Meanwhile, the modulated electronic properties can lower the activation energy for the generation of hydroxyl radicals (center dot OH) from hydrogen peroxide (H2O2), thus leading to a promoted catalytic performance in oxidative desulfurization. This finding may pave a new strategy for tuning metal-free catalysts with highly-active catalytic performance.
KeywordElectronic structure Deep eutectic solvent Hexagonal boron nitride Organic modification Oxidative desulfurization
Funding OrganizationNational Nat-ural Science Foundation of China ; Chinese Postdoctoral Science Foundation ; Natural Science Foundation of Jiangsu Province ; LiaoNing Revitalization Talents Program
DOI10.1016/j.mcat.2021.111757
Indexed BySCI
Languageen
Funding ProjectNational Nat-ural Science Foundation of China[21878133] ; National Nat-ural Science Foundation of China[21908082] ; National Nat-ural Science Foundation of China[22008094] ; Chinese Postdoctoral Science Foundation[2019M651742] ; Chinese Postdoctoral Science Foundation[2019M651743] ; Natural Science Foundation of Jiangsu Province[BK20190852] ; LiaoNing Revitalization Talents Program[XLYC1807175]
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
WOS IDWOS:000686886000001
PublisherELSEVIER
Citation statistics
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/159262
Collection中国科学院金属研究所
Corresponding AuthorZhu, Wenshuai
Affiliation1.Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Jiangsu, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
3.Jiangsu Univ, Sch Pharm, Zhenjiang 212013, Jiangsu, Peoples R China
4.Sun Yat sen Univ, Sch Chem, Fine Chem Ind Res Inst, Guangzhou 510275, Peoples R China
Recommended Citation
GB/T 7714
Lu, Linjie,Zhang, Bingsen,Li, Hongping,et al. Controllable electronic effect via deep eutectic solvents modification for boosted aerobic oxidative desulfurization[J]. MOLECULAR CATALYSIS,2021,512:8.
APA Lu, Linjie.,Zhang, Bingsen.,Li, Hongping.,Chao, Yanhong.,Li, Yujun.,...&Zhu, Wenshuai.(2021).Controllable electronic effect via deep eutectic solvents modification for boosted aerobic oxidative desulfurization.MOLECULAR CATALYSIS,512,8.
MLA Lu, Linjie,et al."Controllable electronic effect via deep eutectic solvents modification for boosted aerobic oxidative desulfurization".MOLECULAR CATALYSIS 512(2021):8.
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