Role of Catalytic Materials on Conversion of Sulfur Species for Room Temperature Sodium-Sulfur Battery

doi:10.1002/eem2.12224

IMR OpenIR

	Role of Catalytic Materials on Conversion of Sulfur Species for Room Temperature Sodium-Sulfur Battery
	Yang, Zhenzhen 1,2; Xiao, Ru 2,3; Zhang, Xiaoyin 2,3; Wang, Xin 1,2; Zhang, Dong 1,2; Sun, Zhenhua 2,3; Li, Feng 2,3
通讯作者	Zhang, Dong(dongzhang@jlu.edu.cn) ; Sun, Zhenhua(zhsun@imr.ac.cn) ; Li, Feng(fli@imr.ac.cn)
	2021-08-22
发表期刊	ENERGY & ENVIRONMENTAL MATERIALS
页码	18
摘要	Room temperature sodium-sulfur (RT Na-S) battery with high theoretical energy density and low cost has spurred tremendous interest, which is recognized as an ideal candidate for large-scale energy storage applications. However, serious sodium polysulfide shutting and sluggish reaction kinetics lead to rapid capacity decay and poor Coulombic efficiency. Recently, catalytic materials capable of adsorbing and catalyzing the conversion of polysulfides are profiled as a promising method to improve electrochemical performance. In this review, the research progress is summarized that the application of catalytic materials in RT Na-S battery. For the role of catalyst on the conversion of sulfur species, specific attention is focused on the influence factors of reaction rate during different redox processes. Various catalytic materials based on lightweight and high conductive carbon materials, including heteroatom-doped carbon, metals and metal compounds, single-atom and heterostructure, promote the reaction kinetic via lowered energy barrier and accelerated charge transfer. Additionally, the adsorption capacity of the catalytic materials is the key to the catalytic effect. Particular attention to the interaction between polysulfides and sulfur host materials is necessary for the exploration of catalytic mechanism. Lastly, the challenges and outlooks toward the desired design of efficient catalytic materials for RT Na-S battery are discussed.
关键词	adsorption capacity catalytic materials reaction kinetics room temperature sodium-sulfur battery
资助者	National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; LiaoNing Revitalization Talents Program ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; Special Projects of the Central Government in Guidance of Local Science and Technology Development
DOI	10.1002/eem2.12224
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[52020105010] ; National Natural Science Foundation of China[51972313] ; National Natural Science Foundation of China[51927803] ; National Natural Science Foundation of China[52072378] ; National Natural Science Foundation of China[51902316] ; National Natural Science Foundation of China[51525206] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA22010602] ; LiaoNing Revitalization Talents Program[XLYC1908015] ; Youth Innovation Promotion Association of the Chinese Academy of Sciences[Y201942] ; Special Projects of the Central Government in Guidance of Local Science and Technology Development[2020JH6/10500024]
WOS研究方向	Materials Science
WOS类目	Materials Science, Multidisciplinary
WOS记录号	WOS:000687087000001
出版者	WILEY
引用统计	被引频次：34[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/159290
专题	中国科学院金属研究所
通讯作者	Zhang, Dong; Sun, Zhenhua; Li, Feng
作者单位	1.Jilin Univ, Coll Phys, Key Lab Phys & Technol Adv Battery, Minist Educ, Changchun 130012, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Yang, Zhenzhen,Xiao, Ru,Zhang, Xiaoyin,et al. Role of Catalytic Materials on Conversion of Sulfur Species for Room Temperature Sodium-Sulfur Battery[J]. ENERGY & ENVIRONMENTAL MATERIALS,2021:18.
APA	Yang, Zhenzhen.,Xiao, Ru.,Zhang, Xiaoyin.,Wang, Xin.,Zhang, Dong.,...&Li, Feng.(2021).Role of Catalytic Materials on Conversion of Sulfur Species for Room Temperature Sodium-Sulfur Battery.ENERGY & ENVIRONMENTAL MATERIALS,18.
MLA	Yang, Zhenzhen,et al."Role of Catalytic Materials on Conversion of Sulfur Species for Room Temperature Sodium-Sulfur Battery".ENERGY & ENVIRONMENTAL MATERIALS (2021):18.