| Polyelectrolytes of Inorganic Polyoxometalates: Acids, Salts, and Complexes | |
| Lu, Zhuo-Qun1; Zhang, Lan-Lan1; Yan, Yukun2; Wang, Wei1 | |
| Corresponding Author | Wang, Wei(weiwang@nankai.edu.cn) |
| 2021-07-27 | |
| Source Publication | MACROMOLECULES
 |
| ISSN | 0024-9297 |
| Volume | 54Issue:14Pages:6891-6900 |
| Abstract | Hybrid polyelectrolytes comprising a polynorbornene backbone and pendant polyoxometalate (POM) groups, with different degrees of polymerization (DP = 100, 200, and 400), are described. The tetrabutylammonium counterions associated with the POM [(P2V3W15O62)(9-); molecular weight = 3964 Da] groups were exchanged for protons and alkali-metal cations by two cation-exchange methods, without breaking the covalent bond between the POM cluster and the polymer chain. The structural integrity of the POM clusters, which is maintained in anionic polyelectrolytes with ionization numbers ranging from 1.1-4.8 to above six, enables their combination with chiral organic cations to induce chiroptical activity in POMs and with polycations to form polyelectrolyte complexes. We compared the ionization behavior of POM polyelectrolytes with those of POM hybrids and inorganic POM clusters. POM polyelectrolytes have promising applications in electrochemistry, catalysis, and materials science, as well as in electrochromic and photochromic devices. |
| Funding Organization | National Natural Science Foundation of China |
| DOI | 10.1021/acs.macromol.1c00783 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[NSFC 92061120] |
| WOS Research Area | Polymer Science |
| WOS Subject | Polymer Science |
| WOS ID | WOS:000679398200027 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/159682 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Wang, Wei |
| Affiliation | 1.Nankai Univ, Inst Polymer Chem, Ctr Synthet Soft Mat, Minist Educ,Key Lab Funct Polymer Mat, Tianjin 300071, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China |
| Recommended Citation GB/T 7714 | Lu, Zhuo-Qun,Zhang, Lan-Lan,Yan, Yukun,et al. Polyelectrolytes of Inorganic Polyoxometalates: Acids, Salts, and Complexes[J]. MACROMOLECULES,2021,54(14):6891-6900. |
| APA | Lu, Zhuo-Qun,Zhang, Lan-Lan,Yan, Yukun,&Wang, Wei.(2021).Polyelectrolytes of Inorganic Polyoxometalates: Acids, Salts, and Complexes.MACROMOLECULES,54(14),6891-6900. |
| MLA | Lu, Zhuo-Qun,et al."Polyelectrolytes of Inorganic Polyoxometalates: Acids, Salts, and Complexes".MACROMOLECULES 54.14(2021):6891-6900. |
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