Engineering the Active Sites of Graphene Catalyst: From CO2 Activation to Activate Li-CO2 Batteries

doi:10.1021/acsnano.1c00756

IMR OpenIR

	Engineering the Active Sites of Graphene Catalyst: From CO2 Activation to Activate Li-CO2 Batteries
	Chen, Biao 1,2; Wang, Dashuai 1,2; Zhang, Biao 3,4; Zhong, Xiongwei 1,2; Liu, Yingqi 1,2; Sheng, Jinzhi 1,2; Zhang, Qi 1,2; Zou, Xiaolong 1,2; Zhou, Guangmin 1,2; Cheng, Hui-Ming 1,2,5
通讯作者	Zou, Xiaolong(xlzou@sz.tsinghua.edu.cn) ; Zhou, Guangmin(guangminzhou@sz.tsinghua.edu.cn) ; Cheng, Hui-Ming(hmcheng@sz.tsinghua.edu.cn)
	2021-06-22
发表期刊	ACS NANO
ISSN	1936-0851
卷号	15 期号:6 页码:9841-9850
摘要	As one of the CO2 capture and utilization technologies, Li-CO2 batteries have attracted special interest in the application of carbon neutral. However, the design and fabrication of a low-cost high-efficiency cathode catalyst for reversible Li2CO3 formation and decomposition remains challenging. Here, guided by theoretical calculations, CO2 was utilized to activate the catalytic activity of conventional nitrogen-doped graphene, in which pyridinic-N and pyrrolic-N have a high total content (72.6590) and have a high catalytic activity in both CO2 reduction and evolution reactions, thus activating the reversible conversion of Li2CO3 formation and decomposition. As a result, the designed cathode has a low voltage gap of 2.13 V at 1200 mA g(-1) and long-life cycling stability with a small increase in the voltage gap of 0.12 V after 170 cycles at 500 mA g(-1). Our work suggests a way to design metal-free catalysts with high activity that can be used to activate the performance of Li-CO2 batteries.
关键词	graphene nitrogen configuration active site CO2 activation Li-CO2 batteries
资助者	China Postdoctoral Science Foundation ; Guangdong Innovative and Entrepreneurial Research Team Program ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; Tsinghua Shenzhen International Graduate School ; Shenzhen Geim Graphene Center ; Bureau of Industry and Information Technology of Shenzhen ; Foundation of Science and Technology on Surface Physics and Chemistry Laboratory
DOI	10.1021/acsnano.1c00756
收录类别	SCI
语种	英语
资助项目	China Postdoctoral Science Foundation[2020TQ0159] ; China Postdoctoral Science Foundation[2020M680544] ; China Postdoctoral Science Foundation[2020M680506] ; Guangdong Innovative and Entrepreneurial Research Team Program[2017ZT07C341] ; National Key Research and Development Program of China[2019YFA0705700] ; National Natural Science Foundation of China[52072205] ; Tsinghua Shenzhen International Graduate School ; Shenzhen Geim Graphene Center ; Bureau of Industry and Information Technology of Shenzhen[201901171523] ; Foundation of Science and Technology on Surface Physics and Chemistry Laboratory[WDZC201901]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000665748900054
出版者	AMER CHEMICAL SOC
引用统计	被引频次：59[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/159904
专题	中国科学院金属研究所
通讯作者	Zou, Xiaolong; Zhou, Guangmin; Cheng, Hui-Ming
作者单位	1.Tsinghua Univ, Shenzhen Geim Graphene Ctr, Tsinghua Berkeley Shenzhen Inst, Shenzhen 518055, Peoples R China 2.Tsinghua Univ, Tsinghua Shenzhen Int Grad Sch, Shenzhen 518055, Peoples R China 3.Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300350, Peoples R China 4.Tianjin Univ, Tianjin Key Lab Composite & Funct Mat, Tianjin 300350, Peoples R China 5.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Chen, Biao,Wang, Dashuai,Zhang, Biao,et al. Engineering the Active Sites of Graphene Catalyst: From CO2 Activation to Activate Li-CO2 Batteries[J]. ACS NANO,2021,15(6):9841-9850.
APA	Chen, Biao.,Wang, Dashuai.,Zhang, Biao.,Zhong, Xiongwei.,Liu, Yingqi.,...&Cheng, Hui-Ming.(2021).Engineering the Active Sites of Graphene Catalyst: From CO2 Activation to Activate Li-CO2 Batteries.ACS NANO,15(6),9841-9850.
MLA	Chen, Biao,et al."Engineering the Active Sites of Graphene Catalyst: From CO2 Activation to Activate Li-CO2 Batteries".ACS NANO 15.6(2021):9841-9850.