Effect of glycine addition on the in-vitro corrosion behavior of AZ31 magnesium alloy in Hank's solution | |
Pokharel, Durga Bhakta1,2; Wu, Liping3; Dong, Junhua1,2; Yadav, Amar Prasad1,4; Subedi, Dhruba Babu1,2; Dhakal, Madhusudan1,2; Zha, Lin3; Mu, Xin1; Umoh, Aniefiok Joseph1,2; Ke, Wei3 | |
Corresponding Author | Dong, Junhua(ihdong@imr.ac.cn) |
2021-08-10 | |
Source Publication | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
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ISSN | 1005-0302 |
Volume | 81Pages:97-107 |
Abstract | This study reports on the effect of the addition of Glycine to Hank's solution on the in-vitro corrosion behavior of AZ31 magnesium (Mg) alloy at 37 degrees C and a pH of 7.4 studied by using potentiodynamic polarization (PDP), hydrogen collecting techniques and electrochemical impedance spectroscopy (EIS) in combination with surface characterization techniques such as optical microscopy (OM), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy analysis (XPS). The results reveal that adsorption of glycine initially subdues the dissolution of AZ31 Mg alloy while in long run it enhances the dissolution of the alloy due to the commencement of the chelation effect of glycine with Ca2+ released from hydroxyapatite. The chelation of glycine with Ca2+ induces the formation of cracks in the surface film which further promotes the dissolution of AZ31 Mg alloy thereby forming a porous corrosion products layer on the surface of the alloy. As a result, both the continuous dissolution of AZ31 magnesium alloy and the hydrogen evolution rate (HER) are enhanced with increasing the immersion time in Hank's solution. (c) 2021 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology. |
Keyword | AZ31 Mg alloy Glycine Hank's solution EIS Chelating effect |
Funding Organization | National Natural Science Foundation of China ; National Key Research and Development Program of China |
DOI | 10.1016/j.jmst.2021.01.007 |
Indexed By | SCI |
Language | 英语 |
Funding Project | National Natural Science Foundation of China[51701221] ; National Natural Science Foundation of China[51801219] ; National Key Research and Development Program of China[2017YFB0702302] |
WOS Research Area | Materials Science ; Metallurgy & Metallurgical Engineering |
WOS Subject | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
WOS ID | WOS:000658560600011 |
Publisher | JOURNAL MATER SCI TECHNOL |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/160338 |
Collection | 中国科学院金属研究所 |
Corresponding Author | Dong, Junhua |
Affiliation | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci SYNL, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China 3.Chinese Acad Sci, Environm Corros Ctr, Inst Met Res, Shenyang 110016, Peoples R China 4.Tribhuvan Univ, Cent Dept Chem, Kirtipur, Nepal |
Recommended Citation GB/T 7714 | Pokharel, Durga Bhakta,Wu, Liping,Dong, Junhua,et al. Effect of glycine addition on the in-vitro corrosion behavior of AZ31 magnesium alloy in Hank's solution[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2021,81:97-107. |
APA | Pokharel, Durga Bhakta.,Wu, Liping.,Dong, Junhua.,Yadav, Amar Prasad.,Subedi, Dhruba Babu.,...&Ke, Wei.(2021).Effect of glycine addition on the in-vitro corrosion behavior of AZ31 magnesium alloy in Hank's solution.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,81,97-107. |
MLA | Pokharel, Durga Bhakta,et al."Effect of glycine addition on the in-vitro corrosion behavior of AZ31 magnesium alloy in Hank's solution".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 81(2021):97-107. |
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