Effect of glycine addition on the in-vitro corrosion behavior of AZ31 magnesium alloy in Hank's solution | |
Pokharel, Durga Bhakta1,2; Wu, Liping3; Dong, Junhua1,2; Yadav, Amar Prasad1,4; Subedi, Dhruba Babu1,2; Dhakal, Madhusudan1,2; Zha, Lin3; Mu, Xin1; Umoh, Aniefiok Joseph1,2; Ke, Wei3 | |
通讯作者 | Dong, Junhua(ihdong@imr.ac.cn) |
2021-08-10 | |
发表期刊 | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
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ISSN | 1005-0302 |
卷号 | 81页码:97-107 |
摘要 | This study reports on the effect of the addition of Glycine to Hank's solution on the in-vitro corrosion behavior of AZ31 magnesium (Mg) alloy at 37 degrees C and a pH of 7.4 studied by using potentiodynamic polarization (PDP), hydrogen collecting techniques and electrochemical impedance spectroscopy (EIS) in combination with surface characterization techniques such as optical microscopy (OM), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy analysis (XPS). The results reveal that adsorption of glycine initially subdues the dissolution of AZ31 Mg alloy while in long run it enhances the dissolution of the alloy due to the commencement of the chelation effect of glycine with Ca2+ released from hydroxyapatite. The chelation of glycine with Ca2+ induces the formation of cracks in the surface film which further promotes the dissolution of AZ31 Mg alloy thereby forming a porous corrosion products layer on the surface of the alloy. As a result, both the continuous dissolution of AZ31 magnesium alloy and the hydrogen evolution rate (HER) are enhanced with increasing the immersion time in Hank's solution. (c) 2021 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology. |
关键词 | AZ31 Mg alloy Glycine Hank's solution EIS Chelating effect |
资助者 | National Natural Science Foundation of China ; National Key Research and Development Program of China |
DOI | 10.1016/j.jmst.2021.01.007 |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Natural Science Foundation of China[51701221] ; National Natural Science Foundation of China[51801219] ; National Key Research and Development Program of China[2017YFB0702302] |
WOS研究方向 | Materials Science ; Metallurgy & Metallurgical Engineering |
WOS类目 | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
WOS记录号 | WOS:000658560600011 |
出版者 | JOURNAL MATER SCI TECHNOL |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/160338 |
专题 | 中国科学院金属研究所 |
通讯作者 | Dong, Junhua |
作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci SYNL, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China 3.Chinese Acad Sci, Environm Corros Ctr, Inst Met Res, Shenyang 110016, Peoples R China 4.Tribhuvan Univ, Cent Dept Chem, Kirtipur, Nepal |
推荐引用方式 GB/T 7714 | Pokharel, Durga Bhakta,Wu, Liping,Dong, Junhua,et al. Effect of glycine addition on the in-vitro corrosion behavior of AZ31 magnesium alloy in Hank's solution[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2021,81:97-107. |
APA | Pokharel, Durga Bhakta.,Wu, Liping.,Dong, Junhua.,Yadav, Amar Prasad.,Subedi, Dhruba Babu.,...&Ke, Wei.(2021).Effect of glycine addition on the in-vitro corrosion behavior of AZ31 magnesium alloy in Hank's solution.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,81,97-107. |
MLA | Pokharel, Durga Bhakta,et al."Effect of glycine addition on the in-vitro corrosion behavior of AZ31 magnesium alloy in Hank's solution".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 81(2021):97-107. |
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