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Effect of glycine addition on the in-vitro corrosion behavior of AZ31 magnesium alloy in Hank's solution
Pokharel, Durga Bhakta1,2; Wu, Liping3; Dong, Junhua1,2; Yadav, Amar Prasad1,4; Subedi, Dhruba Babu1,2; Dhakal, Madhusudan1,2; Zha, Lin3; Mu, Xin1; Umoh, Aniefiok Joseph1,2; Ke, Wei3
通讯作者Dong, Junhua(ihdong@imr.ac.cn)
2021-08-10
发表期刊JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
ISSN1005-0302
卷号81页码:97-107
摘要This study reports on the effect of the addition of Glycine to Hank's solution on the in-vitro corrosion behavior of AZ31 magnesium (Mg) alloy at 37 degrees C and a pH of 7.4 studied by using potentiodynamic polarization (PDP), hydrogen collecting techniques and electrochemical impedance spectroscopy (EIS) in combination with surface characterization techniques such as optical microscopy (OM), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy analysis (XPS). The results reveal that adsorption of glycine initially subdues the dissolution of AZ31 Mg alloy while in long run it enhances the dissolution of the alloy due to the commencement of the chelation effect of glycine with Ca2+ released from hydroxyapatite. The chelation of glycine with Ca2+ induces the formation of cracks in the surface film which further promotes the dissolution of AZ31 Mg alloy thereby forming a porous corrosion products layer on the surface of the alloy. As a result, both the continuous dissolution of AZ31 magnesium alloy and the hydrogen evolution rate (HER) are enhanced with increasing the immersion time in Hank's solution. (c) 2021 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
关键词AZ31 Mg alloy Glycine Hank's solution EIS Chelating effect
资助者National Natural Science Foundation of China ; National Key Research and Development Program of China
DOI10.1016/j.jmst.2021.01.007
收录类别SCI
语种英语
资助项目National Natural Science Foundation of China[51701221] ; National Natural Science Foundation of China[51801219] ; National Key Research and Development Program of China[2017YFB0702302]
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号WOS:000658560600011
出版者JOURNAL MATER SCI TECHNOL
引用统计
被引频次:18[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/160338
专题中国科学院金属研究所
通讯作者Dong, Junhua
作者单位1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci SYNL, Shenyang 110016, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China
3.Chinese Acad Sci, Environm Corros Ctr, Inst Met Res, Shenyang 110016, Peoples R China
4.Tribhuvan Univ, Cent Dept Chem, Kirtipur, Nepal
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GB/T 7714
Pokharel, Durga Bhakta,Wu, Liping,Dong, Junhua,et al. Effect of glycine addition on the in-vitro corrosion behavior of AZ31 magnesium alloy in Hank's solution[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2021,81:97-107.
APA Pokharel, Durga Bhakta.,Wu, Liping.,Dong, Junhua.,Yadav, Amar Prasad.,Subedi, Dhruba Babu.,...&Ke, Wei.(2021).Effect of glycine addition on the in-vitro corrosion behavior of AZ31 magnesium alloy in Hank's solution.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,81,97-107.
MLA Pokharel, Durga Bhakta,et al."Effect of glycine addition on the in-vitro corrosion behavior of AZ31 magnesium alloy in Hank's solution".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 81(2021):97-107.
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