Synthesis of hexagonal-shaped Cr3C2@C nanoplatelets and role of their intrinsic properties towards microwave absorption | |
Javid, Muhammad1,2; Qu, Xinghao2; Zhao, Yongpeng1; Huang, Feirong2; Farid, Amjad1,3; Zhang, Hao1; Shah, Asif2; Sammed, Khan Abdul1; Duan, Yuping2; Zhang, Zhidong4; Pan, Lujun1; Dong, Xinglong2 | |
通讯作者 | Pan, Lujun(lpan@dlut.edu.cn) ; Dong, Xinglong(dognxl@dlut.edu.cn) |
2021-04-01 | |
发表期刊 | MATERIALS LETTERS
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ISSN | 0167-577X |
卷号 | 288页码:5 |
摘要 | Core-shell nanomaterials have been considered excellent microwave absorbents due to their unique morphologies and designs. Here, hexagonal-shaped Cr3C2 nanoplatelets coated with carbon shells (Cr3C2@C) were fabricated by an arc discharge plasma process. In as-synthesized Cr3C2@C nanoplatelets a weak ferromagnetism is found with an observable coercivity of 38 Oe, a saturation magnetization of 4 x 10(-1)emu/g, and along with a suitable conductivity of 9.56 x 10(2) Omega(-1)cm(-1). The observed suitable electrical conductivity and inductive magnetism of Cr3C2@C nanoplatelets played a vital role as a magnetic and conductive losses. Intrinsic defect-rich Cr3C2 cores and amorphous carbon shells acted as dielectric polarization centers, wherein the incident electromagnetic wave dissipated through polarization and interfacial losses. The Cr3C2@C nanoplatelets with 30 wt% loadings in the paraffin matrix exhibited a minimum reflection loss of -36.9 dB at the thickness of 1.6 mm. The excellent refelection loss performance of Cr3C2@C nanoplatelets was certified to be a result from the synergetic effects of dielectric/magnetic losses and impedance matching. Furthermore, the Cr3C2@C nanoplatelets exhibited oxidation resistivity at 350 degrees C endorsing their application in harsh atmospheres. (C) 2021 Elsevier B.V. All rights reserved. |
关键词 | Nanocomposites Magnetism Defects Dielectrics Reflection loss |
资助者 | National Natural Science Foundation of China ; Liaoning Revitalization Talents Program |
DOI | 10.1016/j.matlet.2021.129329 |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Natural Science Foundation of China[51972039] ; National Natural Science Foundation of China[51331006] ; Liaoning Revitalization Talents Program[XLYC1902122] |
WOS研究方向 | Materials Science ; Physics |
WOS类目 | Materials Science, Multidisciplinary ; Physics, Applied |
WOS记录号 | WOS:000656806100009 |
出版者 | ELSEVIER |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/160352 |
专题 | 中国科学院金属研究所 |
通讯作者 | Pan, Lujun; Dong, Xinglong |
作者单位 | 1.Dalian Univ Technol, Sch Phys, Dalian 116023, Peoples R China 2.Dalian Univ Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Mat Modificat Laser Ion & Electron Beams, Dalian 116023, Peoples R China 3.Govt Coll Univ Faisalabad, Dept Phys, Faisalabad 38000, Pakistan 4.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China |
推荐引用方式 GB/T 7714 | Javid, Muhammad,Qu, Xinghao,Zhao, Yongpeng,et al. Synthesis of hexagonal-shaped Cr3C2@C nanoplatelets and role of their intrinsic properties towards microwave absorption[J]. MATERIALS LETTERS,2021,288:5. |
APA | Javid, Muhammad.,Qu, Xinghao.,Zhao, Yongpeng.,Huang, Feirong.,Farid, Amjad.,...&Dong, Xinglong.(2021).Synthesis of hexagonal-shaped Cr3C2@C nanoplatelets and role of their intrinsic properties towards microwave absorption.MATERIALS LETTERS,288,5. |
MLA | Javid, Muhammad,et al."Synthesis of hexagonal-shaped Cr3C2@C nanoplatelets and role of their intrinsic properties towards microwave absorption".MATERIALS LETTERS 288(2021):5. |
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