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Encapsulation of Platinum by Titania under an Oxidative Atmosphere: Contrary to Classical Strong Metal-Support Interactions
Liu, Shaofeng1,2,3; Qi, Haifeng1,3; Zhou, Junhui4; Xu, Wei5; Niu, Yiming6; Zhang, Bingsen6; Zhao, Yang1; Liu, Wei1; Ao, Zhimin4; Kuang, Zhichong1,3; Li, Lin1; Wang, Meng7; Wang, Junhu1,2
Corresponding AuthorZhang, Bingsen(bszhang@imr.ac.cn) ; Ao, Zhimin(zhimin.ao@gdut.edu.cn) ; Wang, Junhu(wangjh@dicp.ac.cn)
2021-05-21
Source PublicationACS CATALYSIS
ISSN2155-5435
Volume11Issue:10Pages:6081-6090
AbstractClassical strong metal-support interaction (SMSI) has attracted intensive attention in the heterogeneous catalysis field; however, its crystalline TiOx overlayer and reversible feature often curtail the effect of classical SMSI on enhancing the catalytic performance of supported metal catalysts in oxidation reactions, especially at elevated temperatures. Here, we report the evidence that Pt nanoparticles can be encapsulated by an amorphous and permeable TiOx cover layer in Pt/TiO2 catalysts under an oxidative atmosphere, where the keys are the utilization of melamine, followed by annealing in nitrogen flow and further calcination at 800 degrees C in air. More importantly, the formed overlayer is stabilized against re-oxidation at 400-600 degrees C in air, in sharp contrast to the retreat of the TiOx overlayer by subsequent oxidation treatment in classical SMSI. Such an extraordinary strategy is further demonstrated on titania-supported Pd and Rh nanoparticles, paving a promising way for designing supported platinum group metal-based catalysts with high activity and stability.
Keywordstrong metal-support interaction (smsi) platinum group metals titania encapsulation oxidative atmosphere
Funding OrganizationNational Natural Science Foundation of China ; International Partnership Program of Chinese Academy of Sciences ; State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics
DOI10.1021/acscatal.1c01347
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[21476232] ; National Natural Science Foundation of China[21777033] ; National Natural Science Foundation of China[21961142006] ; International Partnership Program of Chinese Academy of Sciences[121421KYSB20170020] ; State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics[N-16-07]
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
WOS IDWOS:000656056200016
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/160359
Collection中国科学院金属研究所
Corresponding AuthorZhang, Bingsen; Ao, Zhimin; Wang, Junhu
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Mossbauer Effect Data Ctr, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Guangdong Univ Technol, Sch Environm Sci & Engn, Guangzhou Key Lab Environm Catalysis & Pollut Con, Inst Environm Hlth & Pollut Control, Guangzhou 510080, Peoples R China
5.Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China
6.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
7.Nagoya Univ, Dept Chem & Biotechnol, Sch Engn, Nagoya, Aichi 4648603, Japan
Recommended Citation
GB/T 7714
Liu, Shaofeng,Qi, Haifeng,Zhou, Junhui,et al. Encapsulation of Platinum by Titania under an Oxidative Atmosphere: Contrary to Classical Strong Metal-Support Interactions[J]. ACS CATALYSIS,2021,11(10):6081-6090.
APA Liu, Shaofeng.,Qi, Haifeng.,Zhou, Junhui.,Xu, Wei.,Niu, Yiming.,...&Wang, Junhu.(2021).Encapsulation of Platinum by Titania under an Oxidative Atmosphere: Contrary to Classical Strong Metal-Support Interactions.ACS CATALYSIS,11(10),6081-6090.
MLA Liu, Shaofeng,et al."Encapsulation of Platinum by Titania under an Oxidative Atmosphere: Contrary to Classical Strong Metal-Support Interactions".ACS CATALYSIS 11.10(2021):6081-6090.
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