Revealing the Structure Evolution of Heterogeneous Pd Catalyst in Suzuki Reaction via the Identical Location Transmission Electron Microscopy

doi:10.1021/acsnano.1c00486

IMR OpenIR

	Revealing the Structure Evolution of Heterogeneous Pd Catalyst in Suzuki Reaction via the Identical Location Transmission Electron Microscopy
	Shi, Wen 1,2; Niu, Yiming 1,2; Li, Shunlin 3,4; Zhang, Liyun 1; Zhang, Ying 1; Botton, Gianluigi A.5; Wan, Ying 3,4; Zhang, Bingsen 1,2
通讯作者	Wan, Ying(ywan@shnu.edu.cn) ; Zhang, Bingsen(bszhang@imr.ac.cn)
	2021-05-25
发表期刊	ACS NANO
ISSN	1936-0851
卷号	15 期号:5 页码:8621-8637
摘要	The mechanism of palladium nanoparticles (PdNPs)-catalyzed cross-coupling reactions has been the subject of intense debate since the recognition of catalytic active sites involving a wide array of dynamic changed Pd species. Here, through the combination of the hot filtration experiment together with the recently developed identical location transmission electron microscopy (IL-TEM) method, the delicate structure evolution of highly dispersed Pd NPs supported on oxygen-functionalized carbon nanotubes (Pd/oCNTs) as well as the kinetics properties of derived dissolved species in liquid phase were systemically investigated in the Suzuki-Miyaura reaction. The result indicates that the leached Pd components caused by the strong adsorption of reactants might have a significant contribution to the coupling products, and the degree for different substrates follows the order of iodobenzene > phenylboronic acid > bromobenzene. Meanwhile, the typical three sequential behaviors of supported Pd NPs, including dissolution, deposition, and growth, along with the increase of the conversion throughout the reaction were spatiotemporally observed by tracking the evolution of individually identifiable NPs. The performed work not only provides direct evidence for the interaction between Pd NPs surface with reactants on atomic scale but also gives a valuable reference for fundamentally understanding the mechanism of the heterogeneous Pd-catalyzed Suzuki coupling process as well as rational design of next-generation catalysts with high efficiency and reusability for synthetic applications.
关键词	pallidum nanoparticle heterogeneous catalysis Suzuki-Miyaura reaction structure evolution identical location transmission electron microscopy (IL-TEM)
资助者	National Natural Science Foundation of China ; Liao Ning Revitalization Talents Program ; Research Fund of SYNL ; Youth Innovation Promotion Association CAS
DOI	10.1021/acsnano.1c00486
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[21773269] ; National Natural Science Foundation of China[22072164] ; National Natural Science Foundation of China[21761132025] ; National Natural Science Foundation of China[51932005] ; National Natural Science Foundation of China[21703262] ; Liao Ning Revitalization Talents Program[XLYC1807175] ; Research Fund of SYNL ; Youth Innovation Promotion Association CAS[2015152]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000656994100061
出版者	AMER CHEMICAL SOC
引用统计	被引频次：26[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/160435
专题	中国科学院金属研究所
通讯作者	Wan, Ying; Zhang, Bingsen
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Shanghai Normal Univ, Shanghai Key Lab Rare Earth Funct Mat, Minist Educ, Key Lab Resource Chem, Shanghai 200234, Peoples R China 4.Shanghai Normal Univ, Dept Chem, Shanghai 200234, Peoples R China 5.McMastcr Univ, Dept Mat Sci & Engn, Hamilton, ON L8S 4M1, Canada
推荐引用方式 GB/T 7714	Shi, Wen,Niu, Yiming,Li, Shunlin,et al. Revealing the Structure Evolution of Heterogeneous Pd Catalyst in Suzuki Reaction via the Identical Location Transmission Electron Microscopy[J]. ACS NANO,2021,15(5):8621-8637.
APA	Shi, Wen.,Niu, Yiming.,Li, Shunlin.,Zhang, Liyun.,Zhang, Ying.,...&Zhang, Bingsen.(2021).Revealing the Structure Evolution of Heterogeneous Pd Catalyst in Suzuki Reaction via the Identical Location Transmission Electron Microscopy.ACS NANO,15(5),8621-8637.
MLA	Shi, Wen,et al."Revealing the Structure Evolution of Heterogeneous Pd Catalyst in Suzuki Reaction via the Identical Location Transmission Electron Microscopy".ACS NANO 15.5(2021):8621-8637.