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Na-CO2 battery with NASICON-structured solid-state electrolyte
Tong, Zizheng1; Wang, Shu-Bo1; Fang, Mu-Huai1; Lin, Yen-Ting1; Tsai, Kun-Ta2; Tsai, Sung-Yu2; Yin, Li-Chang3; Hu, Shu-Fen4; Liu, Ru-Shi1
Corresponding AuthorYin, Li-Chang(lcyin@imr.ac.cn) ; Hu, Shu-Fen(sfhu.hu@ntnu.edu.tw) ; Liu, Ru-Shi(rsliu@ntu.edu.tw)
2021-07-01
Source PublicationNANO ENERGY
ISSN2211-2855
Volume85Pages:9
AbstractUtilizing CO2 as cathode gas, Na-CO2 battery has been intensively studied due to its potential application in the exploration of Mars, where CO2 takes up 96% of the atmosphere. However, evaporation of the flammable liquid electrolyte restricts the practical application of the Na-CO2 battery. Herein, a solid-state Na-CO2 battery has been fabricated with the help of a plastic crystal electrolyte and kinetically stable interphase. The succinonitrilebased plastic crystal electrolyte interphase makes an intimate contact between Na3Zr2Si2PO12(NZSP) and cathode, thereby promotes the interfacial charge transfer. Simultaneously, the kinetically stable interphase on the anode side is revealed by the cooperation of theoretical calculation and experiments. The kinetically stable interphase protects the NZSP from the continuous interfacial parasitic reaction. The as-proposed solid-state Na-CO2 battery delivers a life span of 50 cycles at 100 mA g(-1) with a potential gap of 1.4 V. This study makes solid-state electrolyte Na-CO2 battery an attractive prospect in future applications.
KeywordSolid-state Na-CO2 battery NASICON NZSP Solid-state battery Na-metal battery
Funding OrganizationMinistry of Science and Technology (MOST) of Taiwan ; National Natural Science Foundation of China (NSFC)
DOI10.1016/j.nanoen.2021.105972
Indexed BySCI
Language英语
Funding ProjectMinistry of Science and Technology (MOST) of Taiwan[MOST 109-2113-M-002-020-MY3] ; Ministry of Science and Technology (MOST) of Taiwan[MOST 109-2112-M-003-011] ; Ministry of Science and Technology (MOST) of Taiwan[MOST 107-2113-M-002-008-MY3] ; Ministry of Science and Technology (MOST) of Taiwan[MOST 106-2112-M-003-007-MY3] ; National Natural Science Foundation of China (NSFC)[51972312] ; National Natural Science Foundation of China (NSFC)[51472249]
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
WOS IDWOS:000663443300002
PublisherELSEVIER
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/160516
Collection中国科学院金属研究所
Corresponding AuthorYin, Li-Chang; Hu, Shu-Fen; Liu, Ru-Shi
Affiliation1.Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan
2.China Glaze Co Ltd, 136,Sect 4,Chung Hsing Rd, Hsinchu 31061, Taiwan
3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
4.Natl Taiwan Normal Univ, Dept Phys, Taipei 116, Taiwan
Recommended Citation
GB/T 7714
Tong, Zizheng,Wang, Shu-Bo,Fang, Mu-Huai,et al. Na-CO2 battery with NASICON-structured solid-state electrolyte[J]. NANO ENERGY,2021,85:9.
APA Tong, Zizheng.,Wang, Shu-Bo.,Fang, Mu-Huai.,Lin, Yen-Ting.,Tsai, Kun-Ta.,...&Liu, Ru-Shi.(2021).Na-CO2 battery with NASICON-structured solid-state electrolyte.NANO ENERGY,85,9.
MLA Tong, Zizheng,et al."Na-CO2 battery with NASICON-structured solid-state electrolyte".NANO ENERGY 85(2021):9.
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