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Effect of graphite exfoliation degree on the corrosion protection for epoxy composite coating
Zheng, Hongpeng1,2; Zhou, Yanli1; Shao, Yawei1; Guo, Mengying1; Njoku, Demian I.3; Wang, Fuhui1,2
通讯作者Shao, Yawei(shaoyawei@hrbeu.edu.cn)
2021-06-01
发表期刊COMPOSITES COMMUNICATIONS
ISSN2452-2139
卷号25页码:6
摘要Four kinds of graphite derivatives in different exfoliation degrees were synthesized via modified Hummers' method by controlling the mass ration of graphite and KMnO4. The modified graphite derivatives (GUF) were synthesized through chemical modification with the prepolymer of urea-formaldehyde. Results of Raman spectroscopy (Raman) and Scanning electron microscopy (SEM) revealed that the layer exfoliation was affected by oxidation degree during the preparation of graphene oxide (GO). The highly exfoliated GO was fully modified by UF resin and presented excellent compatibility with epoxy resin. The data of electrochemical impedance spectra (EIS) verified the optimal corrosion resistance of GUF/EP composite coating with the highly exfoliated GO sheets. The data of localized electrochemical impedance spectroscopy (LEIS) demonstrated that the highly exfoliated modified GO exhibited slight galvanic corrosion in the defective coatings.
关键词Epoxy Graphene oxide Corrosion Modification Urea-formaldehyde
资助者national key research and development plan ; Ministry of Science and Technology China ; China Postdoctoral Science Foundation
DOI10.1016/j.coco.2021.100751
收录类别SCI
语种英语
资助项目national key research and development plan ; Ministry of Science and Technology China[2016YFB0300604] ; China Postdoctoral Science Foundation[2020M680962]
WOS研究方向Materials Science
WOS类目Materials Science, Composites
WOS记录号WOS:000663431700004
出版者ELSEVIER SCI LTD
引用统计
被引频次:6[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/160594
专题中国科学院金属研究所
通讯作者Shao, Yawei
作者单位1.Harbin Engn Univ, Coll Mat Sci & Chem Engn, Nantong ST 145, Harbin 150001, Peoples R China
2.Northeastern Univ, Shenyang Natl Lab Mat Sci, 3-11 Wenhua Rd, Shenyang 110819, Peoples R China
3.Chinese Acad Sci, Inst Met Res, Wencui Rd 62, Shenyang 110016, Peoples R China
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GB/T 7714
Zheng, Hongpeng,Zhou, Yanli,Shao, Yawei,et al. Effect of graphite exfoliation degree on the corrosion protection for epoxy composite coating[J]. COMPOSITES COMMUNICATIONS,2021,25:6.
APA Zheng, Hongpeng,Zhou, Yanli,Shao, Yawei,Guo, Mengying,Njoku, Demian I.,&Wang, Fuhui.(2021).Effect of graphite exfoliation degree on the corrosion protection for epoxy composite coating.COMPOSITES COMMUNICATIONS,25,6.
MLA Zheng, Hongpeng,et al."Effect of graphite exfoliation degree on the corrosion protection for epoxy composite coating".COMPOSITES COMMUNICATIONS 25(2021):6.
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