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Self-healing epoxy coating based on tung oil-containing microcapsules for corrosion protection
Li, Jianyang1,2; Shi, Hongwei1; Liu, Fuchun1; Han, En-Hou1
通讯作者Shi, Hongwei(hwshi@imr.ac.cn)
2021-07-01
发表期刊PROGRESS IN ORGANIC COATINGS
ISSN0300-9440
卷号156页码:11
摘要In this work, urea-formaldehyde (UF) microcapsules loaded with tung oil were prepared by in-situ polymerization. The mean diameter of the obtained microcapsules was 8.5 mu m. The self-healing coating was prepared by the addition of 5 wt.% microcapsules into an epoxy matrix and then painted on the AA2024 substrate. The effect on the coating properties after the incorporation of microcapsules was investigated by adhesion tests and electrochemical impedance spectroscopy (EIS). It is found that 5 wt.% microcapsules in coating formulations did not impart a significant negative effect on coating properties. SEM and EIS tests were used to evaluate the selfhealing effect. According to the fitting results of the EIS data on the scratched samples, the new film that formed by the polymerization of tung oil at the scratched area in the self-healing coating displays a resistance value of more than 106 omega.cm2, which is much higher than 103 omega.cm2 of the oxide layer in the neat epoxy coating. The neutral salt spray tests also confirm the good anti-corrosion performance of the self-healing coating.
关键词Microcapsules Corrosion protection Epoxy coatings Self-healing EIS
资助者National Natural Science Foundation of China
DOI10.1016/j.porgcoat.2021.106236
收录类别SCI
语种英语
资助项目National Natural Science Foundation of China[51571202]
WOS研究方向Chemistry ; Materials Science
WOS类目Chemistry, Applied ; Materials Science, Coatings & Films
WOS记录号WOS:000663296600006
出版者ELSEVIER SCIENCE SA
引用统计
被引频次:68[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/160650
专题中国科学院金属研究所
通讯作者Shi, Hongwei
作者单位1.Chinese Acad Sci, Inst Met Res, CAS Key Lab Nucl Mat & Safety Assessment, Shenyang 110016, Peoples R China
2.Univ Sci & Technol China, Shenyang 230026, Peoples R China
推荐引用方式
GB/T 7714
Li, Jianyang,Shi, Hongwei,Liu, Fuchun,et al. Self-healing epoxy coating based on tung oil-containing microcapsules for corrosion protection[J]. PROGRESS IN ORGANIC COATINGS,2021,156:11.
APA Li, Jianyang,Shi, Hongwei,Liu, Fuchun,&Han, En-Hou.(2021).Self-healing epoxy coating based on tung oil-containing microcapsules for corrosion protection.PROGRESS IN ORGANIC COATINGS,156,11.
MLA Li, Jianyang,et al."Self-healing epoxy coating based on tung oil-containing microcapsules for corrosion protection".PROGRESS IN ORGANIC COATINGS 156(2021):11.
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