| Highly Efficient Electro-reforming of 5-Hydroxymethylfurfural on Vertically Oriented Nickel Nanosheet/Carbon Hybrid Catalysts: Structure-Function Relationships | |
| Lu, Xingyu1,2; Wu, Kuang-Hsu1,2,3; Zhang, Bingsen1,2; Chen, Junnan1,2; Li, Fan1,2; Su, Bing-Jian4; Yan, Pengqiang1,2; Chen, Jin-Ming4; Qi, Wei1,2 | |
| Corresponding Author | Qi, Wei(wqi@imr.ac.cn) |
| 2021-05-20 | |
| Source Publication | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| ISSN | 1433-7851 |
| Pages | 9 |
| Abstract | Ni-promoted electrocatalytic biomass reforming has shown promising prospect in enabling high value-added product synthesis. Here, we developed a novel hybrid catalyst with Ni nanosheet forests anchored on carbon paper. The hybrid catalyst exhibits high efficiency in electrooxidation of HMF to FDCA coupling with H-2 production in high purity. The Ni nanosheets have small crystal grain sizes with abundant edges, which is able to deliver an efficient HMF oxidation to FDCA (selectivity >99 %) at low potential of 1.36 V-RHE with high stability. The post-reaction structure analysis reveals the Ni nanosheets would transfer electrons to carbon and readily turn into NiOx and Ni(OH)(x) during the reaction. DFT results suggest high valence Ni species would facilitate the chemical adsorption (activation) of HMF revealing the reaction pathway. This work emphasizes the importance of the precise control of Ni activity via atomic structure engineering. |
| Keyword | 5-hydroxymethylfurfural biomass valorization electrocatalytic reforming nickel catalysts structure– function relationship |
| Funding Organization | NSFC of China ; Natural Science Foundation of Liaoning Province of China |
| DOI | 10.1002/anie.202102359 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | NSFC of China[22072163] ; NSFC of China[21761132010] ; NSFC of China[91645114] ; Natural Science Foundation of Liaoning Province of China[2020-YQ-02] ; Natural Science Foundation of Liaoning Province of China[2019-MS-296] |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000652286100001 |
| Publisher | WILEY-V C H VERLAG GMBH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/161288 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | Qi, Wei |
| Affiliation | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Liaoning, Peoples R China 3.Univ New South Wales Sydney, Sch Chem Engn, Kensington, NSW 2052, Australia 4.Natl Synchrotron Radiat Res Ctr, Hsinchu 30076, Taiwan |
| Recommended Citation GB/T 7714 | Lu, Xingyu,Wu, Kuang-Hsu,Zhang, Bingsen,et al. Highly Efficient Electro-reforming of 5-Hydroxymethylfurfural on Vertically Oriented Nickel Nanosheet/Carbon Hybrid Catalysts: Structure-Function Relationships[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2021:9. |
| APA | Lu, Xingyu.,Wu, Kuang-Hsu.,Zhang, Bingsen.,Chen, Junnan.,Li, Fan.,...&Qi, Wei.(2021).Highly Efficient Electro-reforming of 5-Hydroxymethylfurfural on Vertically Oriented Nickel Nanosheet/Carbon Hybrid Catalysts: Structure-Function Relationships.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,9. |
| MLA | Lu, Xingyu,et al."Highly Efficient Electro-reforming of 5-Hydroxymethylfurfural on Vertically Oriented Nickel Nanosheet/Carbon Hybrid Catalysts: Structure-Function Relationships".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021):9. |
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