Effect of Fe Content on the Microstructure, Electrical Resistivity, and Nanoindentation Behavior of Zr60Cu40-xFex Phase-Separated Metallic Glasses

doi:10.11900/0412.1961.2020.00137

IMR OpenIR

	Effect of Fe Content on the Microstructure, Electrical Resistivity, and Nanoindentation Behavior of Zr60Cu40-xFex Phase-Separated Metallic Glasses
	Sun Xiaojun 1,2; He Jie 1,2; Chen Bin 1,2; Zhao Jiuzhou 1,2; Jiang Hongxiang 1; Zhang Lili 1; Hao Hongri 1
通讯作者	He Jie(jiehe@imr.ac.cn)
	2021-05-01
发表期刊	ACTA METALLURGICA SINICA
ISSN	0412-1961
卷号	57 期号:5 页码:675-683
摘要	Liquid-liquid phase separation was used to design phase-separated metallic glasses with special properties. In this work, Zr60Cu40-xFex phase-separated metallic glasses were designed by partial substitution of Cu by Fe in Zr60Cu40 metallic glass. The liquid-liquid phase separation behavior of Zr60Cu40-xFex alloy was investigated. The results show that the miscibility gap of the binary Cu-Fe system can be extended into the Zr60Cu40-xFex system and that liquid-liquid phase separation into Cu-rich and Fe-rich liquids occurred during rapid cooling. On the basis of the behavior of liquid-liquid phase separation of the Zr60Cu40-xFex system, the effect of partial substitution of Cu by Fe on the microstructure and phase formation of the Zr60Cu40-xFex alloys was investigated. The microstructure evolution and the competitive mechanism of phase formation in the as-quenched Zr60Cu40-xFex alloy were discussed. For the Zr60Cu20Fe20 alloy, liquid-liquid phase separation into Cu-rich and Fe-rich liquids and then liquid-glass transition occurred during rapid cooling and resulted in a heterogeneous structure with glassy Fe-rich matrix embedded with glassy Cu-rich nanoparticles. Considering this structure, the electrical properties and nanoindentation behavior of the as-quenched Zr60Cu20Fe20 alloy were examined. The abnormal change in electrical resistivity during crystallization and the effect of nanoscale phase separation on the shear transformation zone of the Zr60Cu20Fe20 alloy were analyzed.
关键词	liquid-liquid phase separation immiscible alloy metallic glass electrical resistivity behavior nanoindentation
资助者	National Natural Science Foundation of China ; Natural Science Foundation of Liaoning Province
DOI	10.11900/0412.1961.2020.00137
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51774264] ; National Natural Science Foundation of China[51974288] ; National Natural Science Foundation of China[51574216] ; Natural Science Foundation of Liaoning Province
WOS研究方向	Metallurgy & Metallurgical Engineering
WOS类目	Metallurgy & Metallurgical Engineering
WOS记录号	WOS:000642002500011
出版者	SCIENCE PRESS
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/161416
专题	中国科学院金属研究所
通讯作者	He Jie
作者单位	1.Chinese Acad Sci, Shi Changxu Innovat Ctr Adv Mat, Inst Met Res, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Sun Xiaojun,He Jie,Chen Bin,et al. Effect of Fe Content on the Microstructure, Electrical Resistivity, and Nanoindentation Behavior of Zr60Cu40-xFex Phase-Separated Metallic Glasses[J]. ACTA METALLURGICA SINICA,2021,57(5):675-683.
APA	Sun Xiaojun.,He Jie.,Chen Bin.,Zhao Jiuzhou.,Jiang Hongxiang.,...&Hao Hongri.(2021).Effect of Fe Content on the Microstructure, Electrical Resistivity, and Nanoindentation Behavior of Zr60Cu40-xFex Phase-Separated Metallic Glasses.ACTA METALLURGICA SINICA,57(5),675-683.
MLA	Sun Xiaojun,et al."Effect of Fe Content on the Microstructure, Electrical Resistivity, and Nanoindentation Behavior of Zr60Cu40-xFex Phase-Separated Metallic Glasses".ACTA METALLURGICA SINICA 57.5(2021):675-683.