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Reduction of structural hierarchy translates into variable influence on the performance of boron nitride aerogel
Pan, Jingjing1,2; Wang, Jingyang1
通讯作者Wang, Jingyang(jywang@imr.ac.cn)
2021-03-19
发表期刊ISCIENCE
卷号24期号:3页码:27
摘要The rise of ceramic aerogel offers traditional ceramics a new window. Alongside the emerging prospects, what is open to explore includes the elegant design of a ceramic aerogel with tailorable inner organizations, what would occur when complex hierarchy exists in such an already intricate system, and how the properties get influenced as the complexity fades. Borrowing the wisdom from supramolecular world, we exquisitely transform BN aerogel from a complex hierarchy to a flatten microstructure based on solvent-induced morphology switch of its supramolecular precursor gel. Such reduction in structural hierarchy has insignificant effect on the thermal conductivity (similar to 0.027 W/(m.K)) but shifts the wettability from hydrophobicity to hydrophilicity and occasions nearly 3-fold difference in ion adsorption rate, as exemplified by lead ions. This work may promote the understanding of special hierarchy existing in delicate systems and inspire other attempts to harness the functionality of aerogels by manipulating structural hierarchy.
资助者National Key R and D Program of China ; National Natural Science Foundation of China
DOI10.1016/j.isci.2021.102251
收录类别SCI
语种英语
资助项目National Key R and D Program of China[2017YFB0703201] ; National Natural Science Foundation of China[51772302]
WOS研究方向Science & Technology - Other Topics
WOS类目Multidisciplinary Sciences
WOS记录号WOS:000631646000086
出版者CELL PRESS
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/161721
专题中国科学院金属研究所
通讯作者Wang, Jingyang
作者单位1.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, Hefei 230026, Peoples R China
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Pan, Jingjing,Wang, Jingyang. Reduction of structural hierarchy translates into variable influence on the performance of boron nitride aerogel[J]. ISCIENCE,2021,24(3):27.
APA Pan, Jingjing,&Wang, Jingyang.(2021).Reduction of structural hierarchy translates into variable influence on the performance of boron nitride aerogel.ISCIENCE,24(3),27.
MLA Pan, Jingjing,et al."Reduction of structural hierarchy translates into variable influence on the performance of boron nitride aerogel".ISCIENCE 24.3(2021):27.
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