An in-situ solidification strategy to block polysulfides in Lithium-Sulfur batteries

doi:10.1016/j.ensm.2021.02.012

IMR OpenIR

	An in-situ solidification strategy to block polysulfides in Lithium-Sulfur batteries
	Chen, Ke 1,2; Fang, Ruopian 3; Lian, Zan 1,4; Zhang, Xiaoyin 1,4; Tang, Pei 1,4; Li, Bo 1,4; He, Kuang 1,4; Wang, Da-wei 3; Cheng, Hui-Ming 1,4,5; Sun, Zhenhua 1,4; Li, Feng 1,4
通讯作者	Sun, Zhenhua(zhsun@imr.ac.cn) ; Li, Feng(fli@imr.ac.cn)
	2021-05-01
发表期刊	ENERGY STORAGE MATERIALS
ISSN	2405-8297
卷号	37 页码:224-232
摘要	Lithium-sulfur (Li-S) batteries have recently emerged as a promising candidate for next-generation energy storage systems. Yet the polysulfide dissolution and shuttle issues cause severe performance degradation, hindering their practical use. Here, we report an in-situ solidification strategy for efficient polysulfide blocking via nucleophilic substitution reactions triggered by 2, 5-dichloro-1, 4-benzoquinone (DCBQ) in the electrolyte. Polysulfides could be covalently fixed by DCBQ in the form of solid organosulfur to enable effective immobilization of polysulfides within the cathode, contributing to high capacity-retention. Moreover, the benzoquinonyl groups of DCBQ were found able to accelerate the lithium-ion transport and promote the sulfur redox reaction kinetics. Consequently, the Li-S cell with DCBQ exhibited good electrochemical performances. This approach demonstrates a novel avenue for polysulfide blocking to boost Li-S battery performance.
关键词	Lithium-Sulfur battery Electrolyte additive Organosulfur Accelerating kinetic Polysulfide blocking
资助者	National Natural Science Foundation of China ; National Key R&D Program of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Special Projects of the Central Government in Guidance of Local Science and Technology Development ; Liaoning Revitalization Talents Program ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; China Petrochemical Cooperation
DOI	10.1016/j.ensm.2021.02.012
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[52020105010] ; National Natural Science Foundation of China[51972313] ; National Natural Science Foundation of China[51525206] ; National Natural Science Foundation of China[51927803] ; National Natural Science Foundation of China[52072378] ; National Key R&D Program of China[2016YFB0100100] ; National Key R&D Program of China[2016YFA0200102] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA22010602] ; Special Projects of the Central Government in Guidance of Local Science and Technology Development[2020JH6/10500024] ; Liaoning Revitalization Talents Program[XLYC1908015] ; Youth Innovation Promotion Association of the Chinese Academy of Sciences[Y201942] ; China Petrochemical Cooperation[218025]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目	Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000632779100009
出版者	ELSEVIER
引用统计	被引频次：60[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/162060
专题	中国科学院金属研究所
通讯作者	Sun, Zhenhua; Li, Feng
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Shanghai Tech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China 3.Univ New South Wales, Sch Chem Engn, Sydney, NSW 2052, Australia 4.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 5.Tsinghua Univ, Tsinghua Berkeley Shenzhen Inst, Shenzhen Geim Graphene Ctr, Shenzhen 518055, Peoples R China
推荐引用方式 GB/T 7714	Chen, Ke,Fang, Ruopian,Lian, Zan,et al. An in-situ solidification strategy to block polysulfides in Lithium-Sulfur batteries[J]. ENERGY STORAGE MATERIALS,2021,37:224-232.
APA	Chen, Ke.,Fang, Ruopian.,Lian, Zan.,Zhang, Xiaoyin.,Tang, Pei.,...&Li, Feng.(2021).An in-situ solidification strategy to block polysulfides in Lithium-Sulfur batteries.ENERGY STORAGE MATERIALS,37,224-232.
MLA	Chen, Ke,et al."An in-situ solidification strategy to block polysulfides in Lithium-Sulfur batteries".ENERGY STORAGE MATERIALS 37(2021):224-232.